Methanol → HCID 20566262, Verbindung

HRID 848065Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 848065
C1(C)C=C(C)C=C(C)C=1S(O)(=O)=[O:10].[C:14]1([S:20]([C:22]2[S:23][CH:24]=[CH:25][CH:26]=2)=[NH:21])[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1.CO.I([O-])(=O)(=O)=O.[Na+]>O>[C:14]1([S:20]([C:22]2[S:23][CH:24]=[CH:25][CH:26]=2)(=[NH:21])=[O:10])[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=1

Komponenten

5

Edukt 3

HCID 887MethanolHCID 23667635Sodium periodateHCID 88772777HCID 88772777, Verbindung

Produkt 1

HCID 20566262HCID 20566262, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 962WaterLösungsmittel

Versuchsvorschrift

10 g. Phenyl-(2-thienyl)-sulphimide mesitylene-sulphonate are dissolved in 200 ml. methanol. A solution of 7 g. sodium periodate in 150 ml. water are added dropwise thereto, whereafter the reaction mixture is stirred for 24 hours at ambient temperature. The reaction mixture is then rendered alkaline and evaporated on a rotary evaporator. The residue obtained is partitioned between water and dichloromethane and the organic phase is evaporated. There are obtained 3.7 g. phenyl-(2-thienyl)-sulphoximide which, after recrystallisation from ethyl acetate/isopropanol, melts at 133° C.

Aufarbeitung

  1. customevaporated on a rotary evaporator
  2. customThe residue obtained
  3. customis partitioned between water and dichloromethane
  4. customthe organic phase is evaporated
  5. customThere are obtained 3.7 g
  6. customphenyl-(2-thienyl)-sulphoximide which, after recrystallisation from ethyl acetate/isopropanol, melts at 133° C.

Quellen und Nachweise

ORD-Eintrag
ord-f81957d4d822446ea1b6ad6d4afd2384
Quelldatensatz
uspto-grants-1981_10
Patentnummer
US04294838

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