Dibenzylphosphate → Silver(1+) dibenzyl phosphate

HRID 864952Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 864952
[P:1]([O-:19])([O:11][CH2:12][C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1)([O:3][CH2:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1)=[O:2].C(=O)([O-])[O-].[Ag+2:24]>C(#N)C.O.[Al]>[P:1]([O-:19])([O:3][CH2:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1)([O:11][CH2:12][C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1)=[O:2].[Ag+:24]

Komponenten

6

Edukt 2

HCID 4193600DibenzylphosphateHCID 178418647HCID 178418647, Verbindung

Produkt 1

HCID 13248164Silver(1+) dibenzyl phosphate

Reagenzien, Katalysatoren, Lösungsmittel 3

HCID 962WaterLösungsmittelHCID 6342AcetonitrileLösungsmittelHCID 5359268AluminumLösungsmittel

Versuchsvorschrift

Dibenzyl phosphate (10 mmole, 2.78 g) is dissolved in a mixture of acetonitrile (20 ml) and water (10 ml). Silver carbonate (10 mmole, 2.76 g) is added, and the mixture is stirred at room temperature in the dark (wrapped in aluminum foil) for 2 hours. Excess of silver carbonate is removed by filtration. The solution is evaporated to dryness, and dried over P2O5 in the dark to constant weight (2 days). Yield of silver dibenzoyl phosphate is 3.61 g.

Aufarbeitung

  1. customExcess of silver carbonate is removed by filtration
  2. customThe solution is evaporated to dryness
  3. dry with materialdried over P2O5 in the dark to constant weight (2 days)

Quellen und Nachweise

ORD-Eintrag
ord-39b55e4f9ff449309a8e74ffe687fd81
Quelldatensatz
uspto-grants-1996_10
Patentnummer
US05565439

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