Peracetic Acid → (6-Methyl-7-oxabicyclo[4.1.0]hept-3-yl)methanol

HRID 872426

Reaktionsgleichung

Reaktionsgleichung von HRID 872426
[CH3:1][C:2]1[CH2:7][CH2:6][CH:5]([CH2:8][OH:9])[CH2:4][CH:3]=1.C(OO)(=[O:12])C>C(OCC)(=O)C>[CH3:1][C:2]12[O:12][CH:7]1[CH2:6][CH:5]([CH2:8][OH:9])[CH2:4][CH2:3]2

Komponenten

4

Edukt 2

HCID 6585Peracetic AcidHCID 5646723-Cyclohexene-1-methanol, 4-methyl-

Produkt 1

HCID 86623394(6-Methyl-7-oxabicyclo[4.1.0]hept-3-yl)methanolAusbeute 95 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 8857Ethyl AcetateLösungsmittel

Versuchsvorschrift

Epoxidation of 12.6 g (0.1 mol) of (4-methylcyclohex-3-enyl)methanol was performed with a 5 percent by weight solution of peroxyacetic acid in ethyl acetate at 65° C. The epoxidized product was purified by distillation and thereby yielded 12 g of (6-methyl-7-oxabicyclo[4.1.0]hept-3-yl)methanol with a purity of 98%.

Aufarbeitung

  1. distillationThe epoxidized product was purified by distillation

Quellen und Nachweise

ORD-Eintrag
ord-31a9f14e942a47a2a60663b414812bce
Quelldatensatz
uspto-grants-2015_03
Patentnummer
US08975349B2

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