Acetic Acid → HCID 86650351, Verbindung

HRID 885782Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 885782
Br[CH2:2][C:3]([O:11][CH3:12])=[CH:4][C:5](=[O:10])[C:6]([F:9])([F:8])[F:7].[C:13]([O-:16])(=[O:15])[CH3:14].[K+].C(O)(=O)C>[Br-].C([N+](CCCC)(CCCC)CCCC)CCC.C(#N)C>[C:13]([O:16][CH2:2][C:3]([O:11][CH3:12])=[CH:4][C:5](=[O:10])[C:6]([F:9])([F:8])[F:7])(=[O:15])[CH3:14]

Komponenten

6

Edukt 3

HCID 176Acetic AcidHCID 517044Potassium AcetateHCID 5153113CID 5153113

Produkt 1

HCID 86650351HCID 86650351, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 74236Tetrabutylammonium BromideKatalysatorHCID 6342AcetonitrileLösungsmittel

Versuchsvorschrift

24.8 g (0.1 mol) of 5-bromo-1,1,1-trifluoro-4-methoxypent-3-en-2-one, 20 g of potassium acetate, 5 g of tetrabutylammonium bromide and 8 g of acetic acid were stirred in 300 ml of acetonitrile at 40° C. for 20 h. The precipitate was filtered off and the solvent was removed completely under reduced pressure.

Aufarbeitung

  1. filtrationThe precipitate was filtered off
  2. customthe solvent was removed completely under reduced pressure

Quellen und Nachweise

ORD-Eintrag
ord-7f330ea03c0e44b48d5c4db88bd3b0d1
Quelldatensatz
uspto-grants-2012_08
Patentnummer
US08242313B2

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