1-Octanol → Octyl Acetate

HRID 916914

Reaktionsgleichung

Reaktionsgleichung von HRID 916914
F[B-](F)(F)F.C(=O)([O-])[O-].[Na+].[Na+].[CH2:12]([OH:20])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19].[C:21](OC=C)(=[O:23])[CH3:22].C(OCCCCCCCC)=C>C1(C)C=CC=CC=1>[C:21]([O:20][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19])(=[O:23])[CH3:22]

Komponenten

7

Edukt 5

HCID 9571-OctanolHCID 7904Vinyl AcetateHCID 10340Sodium CarbonateHCID 26255TetrafluoroborateHCID 702491-(Vinyloxy)octane

Produkt 1

HCID 8164Octyl Acetate

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 1140TolueneLösungsmittel

Reaktionsbedingungen

Temperatur
100 °C

Versuchsvorschrift

To a mixture of bis(1,5-cyclooctadiene)iridium tetrafluoroborate [Ir(cod)2]+BF4− (0.01 mmol) and sodium carbonate (0.6 mmol) in toluene (1.0 ml), 1-octanol (130 mg, 1 mmol) and vinyl acetate (2 mmol) were added, followed by stirring at 100° C. in an atmosphere of argon gas for 2 hours. The reaction mixture was analyzed by gas chromatography to find that 1-octyl vinyl ether and octyl acetate were produced in yields of 70% and 2%, respectively, with a conversion from 1-octanol of 72%.

Aufarbeitung

  1. additionwere added

Quellen und Nachweise

ORD-Eintrag
ord-ec7e3262b7b24ff7afd4a77435999bc8
Quelldatensatz
uspto-grants-2007_09
Patentnummer
US07271297B2

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