1-Octanol → Octyl Acetate

HRID 916915

Reaktionsgleichung

Reaktionsgleichung von HRID 916915
[CH2:1]([OH:9])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[C:10](OC=C)(=[O:12])[CH3:11].C(OCCCCCCCC)=C>C1(C)C=CC=CC=1>[C:10]([O:9][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8])(=[O:12])[CH3:11]

Komponenten

5

Edukt 3

HCID 9571-OctanolHCID 7904Vinyl AcetateHCID 702491-(Vinyloxy)octane

Produkt 1

HCID 8164Octyl Acetate

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 1140TolueneLösungsmittel

Reaktionsbedingungen

Temperatur
100 °C

Versuchsvorschrift

To a mixture of di-μ-chlorobis(1,5-cyclooctadiene)diiridium(I) [Ir(cod)Cl]2 (0.01 mmol) and 4MgCO3—Mg(OH)2-5H2O (0.6 mmol) in toluene (1.0 ml), 1-octanol (130 mg, 1 mmol) and vinyl acetate (2 mmol) were added, followed by stirring at 100° C. in an atmosphere of argon gas for 2 hours. The reaction mixture was analyzed by gas chromatography to find that 1-octyl vinyl ether and octyl acetate were produced in yields of 18% and 3%, respectively, with a conversion from 1-octanol of 44%.

Aufarbeitung

  1. additionwere added

Quellen und Nachweise

ORD-Eintrag
ord-8c19adaadfb84c7bb1c8a3506a968cf5
Quelldatensatz
uspto-grants-2007_09
Patentnummer
US07271297B2

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