Oxygen → 9H-Fluoren-1-ol

HRID 9742

Reaktionsgleichung

Reaktionsgleichung von HRID 9742
[CH:1]1[C:13]2[CH2:12][C:11]3[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=3)[C:5]=2[CH:4]=[CH:3][CH:2]=1.[OH:14]N1C(=O)N(O)C(=O)N(O)C1=O.[C:26]([OH:30])(=O)[CH2:27][CH3:28].O=O>C([O-])(=O)C.[Co+2].C([O-])(=O)C.C([O-])(=O)C.[Mn+2].C([O-])(=O)C>[C:1]1(=[O:14])[C:13]2[C:5]([C:6]3[C:11]([CH:12]=2)=[CH:10][CH:9]=[CH:8][CH:7]=3)=[CH:4][CH:3]=[CH:2]1.[C:26]1([OH:30])[C:27]2[CH2:28][C:13]3[C:5](=[CH:4][CH:3]=[CH:2][CH:1]=3)[C:6]=2[CH:7]=[CH:8][CH:9]=1

Komponenten

8

Edukt 4

HCID 977OxygenHCID 1032Propionic AcidHCID 6853FluoreneHCID 104197231,3,5-Trihydroxy-1,3,5-triazinane-2,4,6-trione

Produkt 2

HCID 960879H-Fluoren-1-olHCID 22281833Fluoreneone

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 6277Cobalt diacetateKatalysatorHCID 12525Manganous AcetateKatalysator

Versuchsvorschrift

A mixture of 1.00 g of fluorene, 0.036 g of hexahydro-1,3,5-trihydroxy-1,3,5-triazine-2,4,6-trione (3% by mole relative to fluorene), 9.0 g of propionic acid, 0.008 g of cobalt(II) acetate.4H2O and 0.008 g of manganese(II) acetate.4H2O was stirred at 120° C. in an atmosphere of oxygene gas (1 atm=0.1 MPa) for 5 hours. The resulting product in the reaction mixture was analyzed by gas chromatography and was found to yield fluorenon and fluorenol in 86% and 1% yields, respectively, at 99% conversion of fluorene.

Quellen und Nachweise

ORD-Eintrag
ord-357e71c8313b4627985e801cce9d4fe8
Quelldatensatz
uspto-grants-2006_08
Patentnummer
US07091342B2

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