Water → HCID 19824186, Verbindung

HRID 981375

Reaktionsgleichung

Reaktionsgleichung von HRID 981375
[OH2:1].[C:2]([C:6]1[CH:11]=[C:10]([N:12]=O)[CH:9]=[C:8]([C:14]([CH3:17])([CH3:16])[CH3:15])[C:7]=1[OH:18])([CH3:5])([CH3:4])[CH3:3].ClCCl.[H][H].[CH3:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29]>[Pd]>[OH:18][C:7]1[C:6]([C:2]([CH3:5])([CH3:4])[CH3:3])=[CH:11][C:10]([NH:12][C:24](=[O:1])[CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:3][CH2:2][CH2:6][CH2:7][CH2:8][CH3:9])=[CH:9][C:8]=1[C:14]([CH3:17])([CH3:16])[CH3:15]

Komponenten

7

Edukt 5

HCID 962WaterHCID 6344DichloromethaneHCID 8058HexaneHCID 70383Phenol, 2,6-bis(1,1-dimethylethyl)-4-nitroso-HCID 178418361HCID 178418361, Verbindung2×

Produkt 1

HCID 19824186HCID 19824186, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 23938PalladiumKatalysator

Versuchsvorschrift

A 2 liter Parr bomb was charged with 210.5 g of 44.6% water wet (0.5 mole, pure, dry) 2,6-di-tert-butyl-4-nitrosophenol, 2.0 g of 5% Pd/C catalyst, 300 ml dichloromethane and 400 ml hexane. The nitrogen purged system was pressurized to 50 psi with hydrogen and the rate of hydrogen uptake noted. Hydrogenation was completed within one hour.

Quellen und Nachweise

ORD-Eintrag
ord-89e4a46da6b64ab080f7764d88a2ecde
Quelldatensatz
uspto-grants-1991_02
Patentnummer
US04990671

Verknüpfte Notizen

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