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Water → Cerous carbonate

HRID 251752
Notes
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Reaction equation

HRID 251752 reaction equation
[N+]([O-])([O-])=[O:2].[Ce+3:5].[N+]([O-])([O-])=[O:7].[N+]([O-])([O-])=[O:11].N[C:15](N)=[O:16].[OH2:18]>C(O)C>[C:15](=[O:16])([O-:11])[O-:18].[Ce+3:5].[C:15](=[O:16])([O-:7])[O-:18].[C:15](=[O:16])([O-:2])[O-:18].[Ce+3:5]
ParticipantsProcedureSources & evidenceReaction notes

Participants

5

Reactant 3

HCID 962Water2×HCID 1176UreaHCID 24948Cerium nitrate

Product 1

HCID 160516Cerous carbonate

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent2×

Procedure

A cerium oxide powder was produced in the same manner as described in Embodiment 1 except 0.5 mol of cerium nitrate was dissolved in a solution of 10 mL of water and 90 mL of ethanol, and then mixed with a solution in which 1.5 mol of urea solution was dissolved in a solution of 10 mL of water and 90 mL of ethanol to obtain a cerium carbonate powder. 1.5 kg of the cerium carbonate powder was placed into an alumina crucible and the decomposed material was removed by thermal treatment in an oxygen atmosphere at 300° C. for 24 hours to obtain 1.2 kg of oxide, which was then calcinated in an oxygen atmosphere at 700° C. for one hour. A cerium oxide powder having a crystal size of 24 nm, a specific surface area of 44 m2/g, a pore distribution, of pores less than and over 3 nm, of 33:67, and an average particle diameter of 68-510 nm, was obtained.

Sources & evidence

ORD record
ord-ad41e5acc428483480718d65e71acc80
Source dataset
uspto-grants-2011_01
DOI
10.6084/m9.figshare.5104873.v1
Patent number
US07867461B2

Reaction notes

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On this pageParticipantsProcedureSources & evidenceReaction notes