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Silicic acid (H2SiO3), disodium salt, pentahydrate

HCID 61495
NotesReactions
Basic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
Substructure searchFind similar structures

Basic information

CAS
10213-79-3
Standard SMILES
O.O.O.O.O.O=[Si]([O-])[O-].[Na+].[Na+]
InChIKey
ADPGKKZKGXANON-UHFFFAOYSA-N
Molecular formula
H10Na2O8Si
Average molar mass
212.14 g/mol
Monoisotopic mass
211.99403237

Overview

See also: Disodium dioxido(oxo)silane pentahydrate (annotation moved to).

Names & identifiers

Preferred name
Silicic acid (H2SiO3), disodium salt, pentahydrate
IUPAC
disodium;dioxido(oxo)silane;pentahydrate
English name
SODIUM METASILICATE PENTAHYDRATE
Molecular formula
H5NaO4Si
Molecular weight
120.11

Names & synonyms

Sodium metasilicate pentahydrateSilicic acid (H2SiO3), disodium salt, pentahydrateSilicic acid, disodium salt, pentahydrateDTXSID0029717DISODIUM METASILICATE PENTAHYDRATERefChem:885447DTXCID40971710213-79-3disodium;dioxido(oxo)silane;pentahydrateMFCD00149176H10Na2O8SiSCHEMBL123472
Show more names
metsogranulardrymetakeiso5aqdorimetakeiso5aqSodiumsilicatehydrateSODIUM SILICATE, PENTAHYDRATESodiumMestasilicatePentahydrateSodium metasilicate pentehydratesodiumsilicatehydrate(na2sio3.5h2o)
SODIUM METASILICATE 5H2OAKOS015913813FS76799NS00113262Sodium oxosilanebis(olate)--water (2/1/5)Sodium metasilicate pentahydrate, >=95.0% (T)F098683disodium;bis(oxidanidyl)-oxidanylidene-silane;pentahydrate

Database identifiers

CAS
10213-79-3

Properties

Computed structural properties

Topological polar surface area
68.2 Ų
Hydrogen bond donors
5
Hydrogen bond acceptors
8
Rotatable bonds
0
Heavy atoms
11
Formal charge
0
Complexity
18.8

Experimental & physicochemical properties

Chemical ClassesOther Classes -> Salts, Basic
Physical Description · 2 items

Dry Powder; Liquid; Dry Powder; CBI

Crystalline powder; [Reference #1] White solid; [Sigma-Aldrich MSDS]

Physicochemical properties

Melting point
1088 °C · 1088°C
Density
2.61 · 2.61
refractive index
1.52 · 1.52
storage temp.
Store at room temperature
form
Solid
color
White
PH
12 · 12,5 (in aqueous solution: 10 g /l , 20 °C)
Odor
odourless
Water Solubility
Soluble in cold water.
Merck
14 · 14,8642
InChI
1S/2Na.O3Si.5H2O/c;;1-4(2)3;;;;;/h;;;5*1H2/q2*+1;-2;;;;;
InChIKey
ADPGKKZKGXANON-UHFFFAOYSA-N

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

GHS classification

GHS Classification · 3 items

Danger

H302: Harmful if swallowed [Warning Acute toxicity, oral]

P260, P264, P264+P265, P270, P280, P301+P317, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P308+P316, P316, P317, P321, P330, P363, P405, and P501 (click each P-code to see the statement)

Hazard information

Regulatory Information · 2 items

Silicic acid (H2SiO3), disodium salt, pentahydrate is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Silicic acid (H2SiO3), disodium salt, pentahydrate are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Sodium metasilicate, pentahydrate: Does not have an individual approval but may be used under an appropriate group standard

Hazards Summary · 1 item

Corrosive to moistened rabbit skin; Sodium metasilicate was not sensitizing in a local lymph node assay study of mice; Similar uses and adverse effects are expected from the hydrous and anhydrous forms (Sodium metasilicate pentahydrate, Sodium metasilicate nonahydrate, Sodium metasilicate, Sodium silicate, and Potassium silicate). One case of occupational contact urticaria reported from sodium silicate; [OECD SIDS: Soluble Silicates - 2004] Causes burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; Harmful by ingestion; [Sigma-Aldrich MSDS] See Sodium metasilicate.

EPA Safer ChemicalChemical: Silicic acid, disodium salt, pentahydrate
Hazard Classes and CategoriesAcute toxicity (Oral) - Category 4

Safety & protection

Chemistry & industry

Uses & manufacturing

Uses · 2 items

Permitted for use as an inert ingredient in non-food pesticide products; [EPA] Alkali metal silicates are used as starting materials for products like silicas and zeolites, in detergents and cleaners, and pulp and paper production; Also used to a lesser extent in soil stabilization and sealing, adhesives and binders (construction materials, paperboard and cardboard, ceramic binders, refractories, welding rods, and foundry molds and cores), surface coatings (titanium dioxide production, paints for masonry and glass, and spray coatings for tunnel construction and mining), water/wastewater treatment, enhanced oil recovery, and textile processing (bleach and dye stabilizing); [OECD SIDS: Soluble Silicates - 2004] Generally regarded as safe (GRAS) by the FDA for use in fruit and vegetable washes, sanitizers for food-contact surfaces, and other indirect food contact uses; [NTP]

Molding and Core Making [Category: Foundry]

U.S. Production2023: 250,000 - <400,000 lb
Consumer UsesNot Known or Reasonably Ascertainable
Industry UsesNot Known or Reasonably Ascertainable
Household ProductsInformation on 33 consumer products that contain Sodium metasilicate pentahydrate in the following categories is provided:
Use Classification · 2 items

EPA Safer Chemical Functional Use Classes -> Processing Aids and Additives

Safer Chemical Classes -> Green circle - The chemical has been verified to be of low concern

General Manufacturing InformationAdhesive Manufacturing
Applications · 2 items

UsesSodium Metasilicate Pentahydrate is used in method for preparing cement accelerator containing Aluminum Sulfate.

Related reactions

8 records
New reaction record
HRID 267175 reaction equation
HRID 267175As productuspto-grants-1976_03
HRID 372174 reaction equation
HRID 372174As reactantuspto-grants-1978_05
HRID 596525 reaction equation
HRID 596525As reactantuspto-grants-1977_03
HRID 839492 reaction equation
HRID 839492As reactantuspto-grants-1978_06
HRID 1390543 reaction equation
HRID 1390543As reactantuspto-grants-1979_02
HRID 1458492 reaction equation
HRID 1458492As reactantuspto-grants-1998_12
HRID 1703745 reaction equation
HRID 1703745As reactantuspto-grants-1978_11
HRID 1732542 reaction equation
HRID 1732542As reactantuspto-grants-1980_12

Compound notes

Loading…

On this pageBasic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
PubChem CID
61495
DTXSID
DTXSID0029717
SMILES
O.O.O.O.O.[Na+].[Na+].[O-][Si]([O-])=O
CAS DataBase Reference
10213 · 10213-79-3(CAS DataBase Reference)
EPA Substance Registry System
Silicic acid (H2SiO3), disodium salt, pentahydrate (10213-79-3)
UNSPSC Code
12352302 · 12352302
NACRES
22 · NA.22
Symbol(GHS)
5 · GHS05,GHS07
Signal word
Danger
Hazard statements
290 · H290-H314-H335
Precautionary statements
260 · P260-P280-P301+P330+P331-P303+P361+P353-P305+P351+P338+P310
target organs
Respiratory system
PPE
3 · Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Codes
C
Risk Statements
34 · 34-37
Safety Statements
26 · 26-36/37/39-45
RIDADR
3253 · UN 3253 8/PG 3
WGK Germany
1 · 1
RTECS
9287500 · VV9287500
TSCA
Yes
HazardClass
8 · 8
PackingGroup
III
HS Code
28391100 · 28391100
Storage Class
8 B · 8B - Non-combustible corrosive hazardous materials
Hazard Classifications
1 Met · Eye Dam. 1Met. Corr. 1Skin Corr. 1BSTOT SE 3
Limited Quantities
5 kg · 5.0 kg (11 lbs) (solid)
Excepted Quantities
Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
Protective Action Criteria (PAC) · 3 items

6.0 [mg/m3]

66 [mg/m3]

400 [mg/m3]

Toxicology

Adverse EffectsDermatotoxin - Skin burns.

Safety data

PPE
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
wgk
1
tsca
Yes
rtecs
VV9287500
ridadr
UN 3253 8/PG 3
hs_code
28391100
risk_code
34-37
Signal word
Danger
Symbol(GHS)
GHS05,GHS07
hazard_code
C
safety_code
26-36/37/39-45
hazard_class
8
Storage Class
8B - Non-combustible corrosive hazardous materials
packing_group
III
target organs
Respiratory system
Hazard statements
H290-H314-H335
Limited Quantities
5.0 kg (11 lbs) (solid)
Excepted Quantities
Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
Hazard Classifications
Eye Dam. 1Met. Corr. 1Skin Corr. 1BSTOT SE 3
Precautionary statements
P260-P280-P301+P330+P331-P303+P361+P353-P305+P351+P338+P310

UsesSodium metasilicate pentahydrate can be used:As a silicate electrolyte in plasma electrolytic oxidation (PEO) coating.For the synthesis of sintered mullite ceramics (3Al2O3·2SiO2) by the co-precipitation method.As a source of silica for the synthesis of silica-zirconia composites for the chromatographic applications.For the synthesis of photo-Fenton catalyst, nontronite, for the degradation of Rhodamine B.As a starting material for the synthesis of zeolite NaA layers on α-Al2O3 supports.

Upstream & downstream products

Upstream raw materials

Sodium silicateSodium hydroxideQuartzFumed Silica

Downstream products

SODIUM METASILICATE NONAHYDRATE

Suppliers102 total

国药集团化学试剂有限公司86-21-63210123 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
Shandong chuangyingchemical Co., Ltd.18853181302 · [email protected]
南通润丰石油化工有限公司66017690 19952660367 · [email protected]
合肥翰刚医药科技有限公司+8618062405514 · [email protected]
山东金悦源新材料有限公司18615186228 · [email protected]
Baoji Guokang Healthchem co.,ltd+8615604608665 15604608665 · [email protected]
Dayang Chem (Hangzhou) Co.,Ltd.+86-0571-88938639 17705817739 · [email protected]
Shenyang Simchoice Chemical Co.,Ltd+86-024-23769576 +86-15040101888 · [email protected]
上海迈瑞尔生化科技有限公司4006356688 18621169109 · [email protected]
山东君冠化工有限公司15910080875 15866633512 · [email protected]
上海晶抗生物工程有限公司021-54721350 13524668266 · [email protected]
阿法埃莎(中国)化学有限公司400-6106006 · [email protected]
上海德默医药科技有限公司400-021-7337 2355568890 · [email protected]
安耐吉化学&3A(安徽泽升科技股份有限公司)400-0056266 · [email protected]
山东源和鑫盛化工贸易有限公司18888228368 17862685855 · [email protected]
山东洛克化工有限公司17653113209 13065062079 · [email protected]
山东西亚化学有限公司13355009207 13355009207 · [email protected]
玛雅试剂+86 (573) 82222445 (0)18006601000 452520369 · [email protected]
HONG KONG IPURE BIOLOGY CO.,LIMITED86 18062405514 18062405514 · [email protected]
四川库利南科技有限公司400-1166-196 18981987031 · [email protected]
天津希恩思生化科技有限公司400 638 7771 · [email protected]
湖南汇百侍生物科技有限公司0731-85526065 13308475853 · [email protected]
南京化学试剂股份有限公司025-58369808 17895012682 · [email protected]
斯百全化学(上海)有限公司021-021-021-67601398-809-809-809 15221380277 · [email protected]
艾科试剂4008-755-333 18080918076 · [email protected]
江苏艾康生物医药研发有限公司025-66113011 13913916777 · [email protected]
苏州亚科科技股份有限公司0512-87182055 13451648594 · [email protected]
北京环宇世纪化学科技有限公司hysj_bj.com
上海将来实业股份有限公司400-0066400 13621662912 · [email protected]
安徽科迪达化工有限公司0554-2106669 · [email protected]
HBCChem, Inc.+1-510-219-6317 · [email protected]
美岚实业(上海)有限公司021-58958189 · [email protected]
常州莱诺斯化学有限公司86-519-86202821
上海爱蝶实业有限公司021-58957966 18930537195 · [email protected]
成都零六生物科技有限公司400-1166-196 13458535857 · [email protected]
天津普西唐生物医药科技有限公司010-60605840 · [email protected]
上海麦克林生化科技股份有限公司15221275939 15221275939 · [email protected]
池州凯隆进出口贸易有限公司[email protected]
Sigma-Aldrich西格玛奥德里奇(上海)贸易有限公司021-61415566 800-8193336 · [email protected]
九鼎化学(上海)科技有限公司4009209199 · [email protected]
广东翁江化学试剂有限公司0751-2815987 13927875076 · [email protected]
昆山中莱特贸易有限公司0512-55170668 13913095008;13770601296 · [email protected]
山东智尚新材料有限公司+8617653113209 · [email protected]
上海珈得尔化学技术有限公司13564435016 13564435016 · [email protected]
湖北兴银河化工有限公司13437271305 · [email protected]
济南金日和化工有限公司0531-81762771 15275167056 · [email protected]
陕西缔都医药化工有限公司+86-29-81139210 +86-17392587031 · [email protected]
艾万拓威达优尔国际贸易(上海)有限公司400-821-8006 · [email protected]
上海西陇生化科技有限公司021-52907766-8042