Sulfuric Acid → 1,3-Benzenediol, O,O'-dihexanoyl-

HRID 1089038Notes

Reaction equation

HRID 1089038 reaction equation
C1(C=CC=C(O)C=1)O.C(OC(=O)CCCCC)(=O)CCCCC.S(=O)(=O)(O)O.C1(C(CCCCCC(O)=O)=C(C(CCCCCC(O)=O)=CC=1)O)O.[C:53]([O:60][C:61]1[CH:66]=[CH:65][CH:64]=[C:63]([O:67][C:68](=[O:74])[CH2:69][CH2:70][CH2:71][CH2:72][CH3:73])[CH:62]=1)(=[O:59])[CH2:54][CH2:55][CH2:56][CH2:57][CH3:58].C(O)(=O)CCCCC>>[C:53]([O:60][C:61]1[CH:66]=[CH:65][CH:64]=[C:63]([O:67][C:68](=[O:74])[CH2:69][CH2:70][CH2:71][CH2:72][CH3:73])[CH:62]=1)(=[O:59])[CH2:54][CH2:55][CH2:56][CH2:57][CH3:58]

Participants

6

Reactant 5

HCID 1118Sulfuric AcidHCID 5054ResorcinolHCID 8892Hexanoic AcidHCID 74918Hexanoic anhydrideHCID 1317166801,3 Dihexanoyloxybenzene (resorcinol dihexanoate)

Product 1

HCID 221596541,3-Benzenediol, O,O'-dihexanoyl-

Conditions

Temperature
100 °C

Procedure

In a reaction vessel, resorcinol is placed with an equimolar amount of hexanoic acid anhydride (from Aldrich Chemicals). Concentrated sulfuric acid (98%) is added to the solution and heated at 100° C. for 3 hours. A crude reaction product was obtained from this acid catalysis containing the 1,3 dihexanoyloxybenzene (resorcinol dihexanoate) and hexanoic acid.

Workup

  1. customA crude reaction product
  2. customwas obtained from this acid catalysis

Sources & evidence

ORD record
ord-8af4821dc68f4d909ec36eb320169f3e
Source dataset
uspto-grants-1990_10
Patent number
US04964870

Reaction notes

Loading…