Sodium ion → Methyl 4-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthyloxy)benzoate

HRID 109098

Reaction equation

HRID 109098 reaction equation
[CH3:1][C:2]1([CH3:15])[c:3]2[cH:4][cH:5][c:6]([OH:14])[cH:7][c:8]2[C:9]([CH3:12])([CH3:13])[CH2:10][CH2:11]1.[CH3:29][S:30][CH3:31].[Cu:32]([Br:33])[Br:34].[H-:16].[I:18][c:19]1[cH:20][cH:21][c:22]([C:23](=[O:24])[O:25][CH3:26])[cH:27][cH:28]1.[Na+:17].[cH:35]1[cH:36][cH:37][n:38][cH:39][cH:40]1>>[CH3:1][C:2]1([CH3:15])[c:3]2[cH:4][cH:5][c:6]([O:14][c:19]3[cH:20][cH:21][c:22]([C:23](=[O:24])[O:25][CH3:26])[cH:27][cH:28]3)[cH:7][c:8]2[C:9]([CH3:12])([CH3:13])[CH2:10][CH2:11]1

Participants

8

Reactant 7

HCID 923Sodium ionHCID 1049PyridineHCID 1068Dimethyl SulfideHCID 24611Copper bromide (CuBr2)HCID 69273Methyl 4-iodobenzoateHCID 166653HydrideHCID 2687865,5,8,8-Tetramethyl-5,6,7,8-tetrahydronaphthalen-2-ol

Product 1

HCID 10337221Methyl 4-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthyloxy)benzoate

Sources & evidence

ORD record
ord-0a6b09427595486e81f19acaaeb7f1e7
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (2/10)

Linked notes

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