Dichloromethane → bis[4-(1,1-dimethylethyl)phenyl]-Iodonium

HRID 1125841

Reaction equation

HRID 1125841 reaction equation
[C:16]([CH3:17])([CH3:18])([CH3:19])[c:20]1[cH:21][cH:22][c:23]([I+:26][c:27]2[cH:28][cH:29][c:30]([C:33]([CH3:34])([CH3:35])[CH3:36])[cH:31][cH:32]2)[cH:24][cH:25]1.[C:44]([C:45]([CH3:46])([CH3:47])[CH3:48])(=[O:49])[Cl:50].[CH2:60]([Cl:61])[Cl:62].[CH3:37][CH2:38][N:39]([CH2:40][CH3:41])[CH2:42][CH3:43].[CH3:51][N:52]([CH3:53])[c:54]1[cH:55][cH:56][n:57][cH:58][cH:59]1.[F:1][C:2]([C:3]([CH2:4][S:5](=[O:6])(=[O:7])[O-:8])([C:9]([F:10])([F:11])[F:12])[OH:13])([F:14])[F:15]>>[C:16]([CH3:17])([CH3:18])([CH3:19])[c:20]1[cH:21][cH:22][c:23]([I+:26][c:27]2[cH:28][cH:29][c:30]([C:33]([CH3:34])([CH3:35])[CH3:36])[cH:31][cH:32]2)[cH:24][cH:25]1.[F:1][C:2]([C:3]([CH2:4][S:5](=[O:6])(=[O:7])[O-:8])([C:9]([F:10])([F:11])[F:12])[O:13][C:44]([C:45]([CH3:46])([CH3:47])[CH3:48])=[O:49])([F:14])[F:15]

Participants

8

Reactant 6

HCID 6344DichloromethaneHCID 8471TriethylamineHCID 142844-(Dimethylamino)pyridineHCID 62493Pivaloyl chlorideHCID 2734849bis[4-(1,1-dimethylethyl)phenyl]-IodoniumHCID 594456952-Hydroxy-2-(trifluoromethyl)-3,3,3-trifluoropropane-1-sulfonic acidanion

Product 2

HCID 2734849bis[4-(1,1-dimethylethyl)phenyl]-IodoniumHCID 594457242-(2,2-Dimethylpropanoyloxy)-3,3,3-trifluoro-2-(trifluoromethyl)propane-1-sulfonate

Sources & evidence

ORD record
ord-05c5464365a64ce0ae92a689126c5ce2
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (7/10)

Linked notes

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