Diisopropylamine → 1-(Trimethylsilylethynyl)-4-(trans-4-pentylcyclohexyl)benzene

Reaction equation

[Br:1][c:2]1[cH:3][cH:4][c:5]([CH:8]2[CH2:9][CH2:10][CH:11]([CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])[CH2:12][CH2:13]2)[cH:6][cH:7]1.[CH3:19][Si:20]([CH3:21])([CH3:22])[C:23]#[CH:24].[CH:25]([NH:26][CH:27]([CH3:28])[CH3:29])([CH3:30])[CH3:31].[Cu:32][I:33]>>[c:2]1([C:24]#[C:23][Si:20]([CH3:19])([CH3:21])[CH3:22])[cH:3][cH:4][c:5]([CH:8]2[CH2:9][CH2:10][CH:11]([CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])[CH2:12][CH2:13]2)[cH:6][cH:7]1

Participants

Reactant 4

HCID 7912Diisopropylamine

HCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)

HCID 66111Trimethylsilylacetylene

HCID 38279031-Bromo-4-(trans-4-pentylcyclohexyl)benzene

Product 1

HCID 152768371-(Trimethylsilylethynyl)-4-(trans-4-pentylcyclohexyl)benzene

Sources & evidence

ORD record: ord-8cc67a7622c443e39ff52c7b4604e268
Source dataset: Training data from https://doi.org/10.1039/C8SC04228D (2/10)
DOI: 10.1039/C8SC04228D

Reaction notes

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