Ethyl Acetate → 3-Methoxy-2-methoxymethoxy-5-(2-oxo-oxazolidin-3-yl)benzaldehyde

HRID 1145231

Reaction equation

HRID 1145231 reaction equation
[Br:55][c:56]1[cH:57][c:58]([O:68][CH3:69])[c:59]([O:64][CH2:65][O:66][CH3:67])[c:60]([CH:61]=[O:62])[cH:63]1.[C:49](=[O:50])([O-:51])[O-:52].[CH3:126][CH2:127][O:128][C:129](=[O:130])[CH3:131].[CH3:7][C:8]1([CH3:9])[c:10]2[cH:11][cH:12][cH:13][c:14]([P:15]([c:16]3[cH:17][cH:18][cH:19][cH:20][cH:21]3)[c:22]3[cH:23][cH:24][cH:25][cH:26][cH:27]3)[c:28]2[O:29][c:30]2[c:31]1[cH:32][cH:33][cH:34][c:35]2[P:36]([c:37]1[cH:38][cH:39][cH:40][cH:41][cH:42]1)[c:43]1[cH:44][cH:45][cH:46][cH:47][cH:48]1.[CH:106](=[CH:107][C:108]([CH:109]=[CH:110][c:111]1[cH:112][cH:113][cH:114][cH:115][cH:116]1)=[O:117])[c:118]1[cH:119][cH:120][cH:121][cH:122][cH:123]1.[CH:70](=[CH:71][C:72]([CH:73]=[CH:74][c:75]1[cH:76][cH:77][cH:78][cH:79][cH:80]1)=[O:81])[c:82]1[cH:83][cH:84][cH:85][cH:86][cH:87]1.[CH:88](=[CH:89][C:90]([CH:91]=[CH:92][c:93]1[cH:94][cH:95][cH:96][cH:97][cH:98]1)=[O:99])[c:100]1[cH:101][cH:102][cH:103][cH:104][cH:105]1.[Cs+:53].[Cs+:54].[O:132]1[CH2:133][CH2:134][O:135][CH2:136][CH2:137]1.[O:1]1[C:2](=[O:6])[NH:3][CH2:4][CH2:5]1.[Pd:124].[Pd:125]>>[O:1]1[C:2](=[O:6])[N:3]([c:56]2[cH:57][c:58]([O:68][CH3:69])[c:59]([O:64][CH2:65][O:66][CH3:67])[c:60]([CH:61]=[O:62])[cH:63]2)[CH2:4][CH2:5]1

Participants

10

Reactant 9

HCID 8857Ethyl AcetateHCID 19660Carbonate IonHCID 23938Palladium2×HCID 312751,4-DioxaneHCID 739492-OxazolidinoneHCID 95417Dibenzylidene acetone3×HCID 104967Cesium cation2×HCID 6360441,1'-(9,9-Dimethyl-9H-xanthene-4,5-diyl)bis(1,1-diphenylphosphine)HCID 115653225-Bromo-3-methoxy-2-(methoxymethoxy)benzaldehyde

Product 1

HCID 574825533-Methoxy-2-methoxymethoxy-5-(2-oxo-oxazolidin-3-yl)benzaldehyde

Sources & evidence

ORD record
ord-8363f62faa0d40e6b467feba0ec2dd9b
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (7/10)

Linked notes

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