Azobisisobutyronitrile → HCID 20513501, compound

HRID 1164057

Reaction equation

HRID 1164057 reaction equation
[CH3:1][O:2][C:3]1[C:8]([CH3:9])=[CH:7][CH:6]=[CH:5][C:4]=1[O:10][C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1.[Br:17]N1C(=O)CCC1=O.N(C(C)(C)C#N)=NC(C)(C)C#N>C1C=CC=CC=1>[CH3:1][O:2][C:3]1[C:8]([CH2:9][Br:17])=[CH:7][CH:6]=[CH:5][C:4]=1[O:10][C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1

Participants

5

Reactant 3

HCID 6547AzobisisobutyronitrileHCID 67184N-bromobutanimideHCID 20082997Phenyl 2-methoxy-3-methylphenyl ether

Product 1

HCID 20513501HCID 20513501, compoundYield 103.5%

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

A mixture of phenyl 2-methoxy-3-methylphenyl ether (6 g), N-bromosuccinimide (5.2 g) and azobisisobutyronitrile (500 mg) in dried benzene (60 ml) was treated in a similar manner to that of Example 14-(3) to give oily phenyl 2-methoxy-3-bromomethylphenyl ether (8.5 g).

Workup

  1. additionwas treated in a similar manner to that of Example 14-(3)

Sources & evidence

ORD record
ord-9585e5e9803040eeb09a1d3008e26a77
Source dataset
uspto-grants-1983_01
Patent number
US04367238

Linked notes

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