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Acrylic Acid → Ethylacrylate acrylic acid acrylonitrile

HRID 1194281
Notes
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Reaction equation

HRID 1194281 reaction equation
[C:1]([O:5][CH2:6][CH3:7])(=[O:4])[CH:2]=[CH2:3].[C:8](#[N:11])[CH:9]=[CH2:10].[C:12]([OH:16])(=[O:15])[CH:13]=[CH2:14].C(S)CCCCCCCCCCC.C(OOCCCCCCCCCCCC)CCCCCCCCCCC.C(OOC(=O)C1C=CC=CC=1)CCC>C1(C)C(C)=CC=CC=1>[CH2:6]([O:5][C:1](=[O:4])[CH:2]=[CH2:3])[CH3:7].[C:12]([OH:16])(=[O:15])[CH:13]=[CH2:14].[C:8](#[N:11])[CH:9]=[CH2:10]
ParticipantsProcedureWorkupSources & evidenceReaction notes

Participants

8

Reactant 6

HCID 6581Acrylic AcidHCID 7855AcrylonitrileHCID 81951-DodecanethiolHCID 8821Ethyl AcrylateHCID 76169Lauryl peroxideHCID 83282Butyl perbenzoate

Product 1

HCID 168852
Ethylacrylate acrylic acid acrylonitrile

Reagents, catalysts & solvents 1

HCID 7237O-XyleneSolvent2×

Procedure

this polymer material was produced by adding to 320g xylene at 100° C. the monomer solution and a catalyst solution over a period of 3 hours. The monomer solution contained 2.900g ethyl acrylate, 76g acrylonitrile, 76g acrylic acid and 3g laurylmercaptan. The catalyst solution contained 26g laurylperoxide and 7g butylperbenzoate in 273g of xylene. The material was highly viscous with comonomer proportions of 95:2.5:2.5.

Workup

  1. customthis polymer material was produced

Sources & evidence

ORD record
ord-b49eff8d34704bb290fcc0074a7ddde4
Source dataset
uspto-grants-1989_03
DOI
10.6084/m9.figshare.5104873.v1
Patent number
US04814215

Reaction notes

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On this pageParticipantsProcedureWorkupSources & evidenceReaction notes