Acetate → 2-(1-Tridecynyl)benzaldehyde

HRID 134464

Reaction equation

[Br:1][c:2]1[c:3]([CH:4]=[O:5])[cH:6][cH:7][cH:8][cH:9]1.[C:49]([O-:50])(=[O:51])[CH3:52].[C:54]([O-:55])(=[O:56])[CH3:57].[CH3:42][CH2:43][N:44]([CH2:45][CH3:46])[CH2:47][CH3:48].[CH:10]#[C:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22].[Pd+2:53].[c:23]1([P:24]([c:25]2[cH:26][cH:27][cH:28][cH:29][cH:30]2)[c:31]2[cH:32][cH:33][cH:34][cH:35][cH:36]2)[cH:37][cH:38][cH:39][cH:40][cH:41]1>>[c:2]1([C:10]#[C:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22])[c:3]([CH:4]=[O:5])[cH:6][cH:7][cH:8][cH:9]1

Participants

Reactant 6

HCID 175Acetate2×

HCID 8471Triethylamine

HCID 11776Triphenylphosphine

HCID 811292-Bromobenzaldehyde

HCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)

HCID 1177541-Tridecyne

Product 1

HCID 136885012-(1-Tridecynyl)benzaldehyde

Sources & evidence

ORD record: ord-a823a92959f5449d802c9ad1f29570cc
Source dataset: Training data from https://doi.org/10.1039/C8SC04228D (9/10)
DOI: 10.1039/C8SC04228D

Linked notes

Loading…