Acetate → Methyl 2-(3-phenoxypropenyl)benzoate

HRID 135292

Reaction equation

HRID 135292 reaction equation
[Br:1][c:2]1[c:3]([C:4](=[O:5])[O:6][CH3:7])[cH:8][cH:9][cH:10][cH:11]1.[C:54]([O-:55])(=[O:56])[CH3:57].[C:59]([O-:60])(=[O:61])[CH3:62].[CH3:44][CH2:45][N:46]([CH2:47][CH3:48])[CH2:49][CH3:50].[CH3:51][C:52]#[N:53].[Pd+2:58].[c:12]1([O:18][CH2:19][CH:20]=[CH2:21])[cH:13][cH:14][cH:15][cH:16][cH:17]1.[c:22]1([CH3:23])[cH:24][cH:25][cH:26][cH:27][c:28]1[P:29]([c:30]1[cH:31][cH:32][cH:33][cH:34][c:35]1[CH3:36])[c:37]1[cH:38][cH:39][cH:40][cH:41][c:42]1[CH3:43]>>[c:2]1([CH:21]=[CH:20][CH2:19][O:18][c:12]2[cH:13][cH:14][cH:15][cH:16][cH:17]2)[c:3]([C:4](=[O:5])[O:6][CH3:7])[cH:8][cH:9][cH:10][cH:11]1

Participants

8

Reactant 7

HCID 175Acetate2×HCID 6342AcetonitrileHCID 8471TriethylamineHCID 11894Methyl 2-bromobenzoateHCID 74458Allyl phenyl etherHCID 80271Tri-o-tolylphosphineHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)

Product 1

HCID 67414986Methyl 2-(3-phenoxypropenyl)benzoate

Sources & evidence

ORD record
ord-b7a5c5ef9d0d448b86bdf7258554718d
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (9/10)

Linked notes

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