Toluene → Bromide ion

HRID 151876Notes

Reaction equation

HRID 151876 reaction equation
[Br:20][CH2:21][CH:22]=[CH:23][C:24]#[C:25][Si:26]([CH3:27])([CH3:28])[CH3:29].[CH3:30][c:31]1[cH:32][cH:33][cH:34][cH:35][cH:36]1.[CH3:37][O:38][C:39]([CH3:40])([CH3:41])[CH3:42].[c:1]1([P:7]([c:8]2[cH:9][cH:10][cH:11][cH:12][cH:13]2)[c:14]2[cH:15][cH:16][cH:17][cH:18][cH:19]2)[cH:2][cH:3][cH:4][cH:5][cH:6]1>>[Br-:20].[c:1]1([P+:7]([c:8]2[cH:9][cH:10][cH:11][cH:12][cH:13]2)([c:14]2[cH:15][cH:16][cH:17][cH:18][cH:19]2)[CH2:21][CH:22]=[CH:23][C:24]#[C:25][Si:26]([CH3:27])([CH3:28])[CH3:29])[cH:2][cH:3][cH:4][cH:5][cH:6]1

Participants

6

Reactant 4

HCID 1140TolueneHCID 11776TriphenylphosphineHCID 15413tert-Butyl methyl etherHCID 572808031-Bromo-5-trimethylsilylpent-2-en-4-yne

Product 2

HCID 259Bromide ionHCID 85418396Triphenyl(5-trimethylsilylpent-2-en-4-ynyl)phosphanium

Sources & evidence

ORD record
ord-c2a13fb9ef314ff4a14f190547987c89
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (9/10)

Reaction notes

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