Tetrafluoroethylene → HCID 178447915, compound

HRID 1653610Notes

Reaction equation

HRID 1653610 reaction equation
[CH2:1]([C@H:4]1[CH2:9][CH2:8][C@H:7]([C:10]2[CH:15]=[CH:14][C:13]([OH:16])=[CH:12][CH:11]=2)[CH2:6][CH2:5]1)[CH2:2][CH3:3].[H-].[Na+].[F:19][C:20]([F:24])=[C:21](F)[F:22]>C1C=CC=CC=1.O1CCCC1>[CH2:1]([C@H:4]1[CH2:5][CH2:6][C@H:7]([C:10]2[CH:15]=[CH:14][C:13]([O:16][C:21]([F:22])=[C:20]([F:24])[F:19])=[CH:12][CH:11]=2)[CH2:8][CH2:9]1)[CH2:2][CH3:3]

Participants

6

Reactant 3

HCID 8301TetrafluoroethyleneHCID 24758Sodium hydrideHCID 178447901HCID 178447901, compound

Product 1

HCID 178447915HCID 178447915, compound

Reagents, catalysts & solvents 2

HCID 241BenzeneSolventHCID 8028TetrahydrofuranSolvent

Conditions

Temperature
140 °C

Procedure

A solution of 10 g of p-(trans-4-n-propylcyclohexyl)phenol in a mixture of 40 ml of benzene and 10 ml of tetrahydrofuran is reacted with sodium hydride analogously to Example 1. After tetrafluoroethene has been condensed in, the mixture is heated at 140° C. for about 20 hours and treated as described in Example 1. p-(trans-4-n-propylcyclohexyl)trifluorovinyloxybenzene is obtained.

Workup

  1. customcondensed in, the mixture
  2. additiontreated

Sources & evidence

ORD record
ord-ad8186fb5b77478cb16f6ce861a808d8
Source dataset
uspto-grants-1995_04
Patent number
US05403512

Reaction notes

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