GlyTouCan:G36918VO → (2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal
Reaction equation
[O:1]=[CH:2][C@@H:3]([C@H:5]([C@H:7]([C@@H:9]([CH2:11][OH:12])[OH:10])[OH:8])[OH:6])[OH:4].[CH2:13]([OH:35])[C@H:14]1[O:19][C@H:18]([O:20][CH2:21][C@H:22]2[O:26][C:25]([OH:29])([CH2:27][OH:28])[C@@H:24]([OH:30])[C@@H:23]2[OH:31])[C@H:17]([OH:32])[C@@H:16]([OH:33])[C@@H:15]1[OH:34]>>[O:1]=[CH:2][C@@H:3]([C@H:5]([C@H:7]([C@@H:9]([CH2:11][OH:12])[OH:10])[OH:8])[OH:6])[OH:4].[CH2:13]([OH:35])[C@H:14]1[O:19][C@H:18]([O:20][CH2:21][C@H:22]2[O:26][C:25]([OH:29])([CH2:27][OH:28])[C@@H:24]([OH:30])[C@@H:23]2[OH:31])[C@H:17]([OH:32])[C@@H:16]([OH:33])[C@@H:15]1[OH:34].[O:1]=[CH:2][C@@H:3]([C@H:5]([C@@H:7]([C@@H:9]([CH2:11][OH:12])[OH:10])[OH:8])[OH:6])[OH:4]Participants
Procedure
Taking into account only components (i) and (ii), which are present in the compositions of the invention in relative proportions of 5-60 and 10-75 weight parts, their proportions on a 100% basis are (i) 5/80-60/70 and (ii) 10/70-75/80, or (i) 6.25-85.7 wt. % and (ii) 14.3-93.75%. The most preferred ratios are (i) 10/60-30/48 (16.7-62.5 wt. % and (ii) 18/48-50/60 (37.5-83.3 wt.). Taking only the disaccharides (ii-a), the relative proportion is (i) 5/65-60/70 (7.7-85.7 wt. %) and (ii-a) 10/70-60/65 (14.3-92.3 wt. %), most preferably (i) 10/55-30/45 (18.2-66.7 wt. %), and (ii-a) 15/45-45/55 (33.3-81.8 wt. %). These ratios apply in particular to the combination of galactose and palatinose. Combinations of these specific monosaccharides and specific disaccharides, for instance galactose and palatinose, exhibit synergism in providing a quick and sustained glucose response.
Sources & evidence
- ORD record
- ord-deb5838061bd4195a92a5609500736ba
- Source dataset
- uspto-grants-2012_04
- Patent number
- US08148350B2
Reaction notes
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