1-(2-Bromo-4-fluorophenyl)ethan-1-one → 4'-Fluoroacetophenone

HRID 1704900

Reaction equation

HRID 1704900 reaction equation
CC(=O)c1ccc(F)cc1Br.CCN(CC)c1ccc2oc(=O)c(-c3nc4ccccc4s3)cc2c1>CCN(C(C)C)C(C)C.CN(C)C=O.CS(C)=O.O.O=C(O)c1ccnc(-c2cc(C(=O)O)ccn2)c1.[Cl][Ir]([Cl])[Cl].c1ccc(-c2nc3ccccc3s2)cc1>CC(=O)c1ccc(F)cc1.CCN(CC)c1ccc2oc(=O)c(-c3[nH+]c4ccccc4s3)cc2c1.[Br-]

Participants

10

Reactant 2

HCID 27363041-(2-Bromo-4-fluorophenyl)ethan-1-oneHCID 206057453-(Benzo[d]thiazol-2-yl)-6-(diethylamino)-2H-chromen-2-one

Product 2

HCID 98284'-FluoroacetophenoneHCID 178463797HCID 178463797, compound

Reagents, catalysts & solvents 6

HCID 81531DiisopropylethylamineReagentHCID 134392-PhenylbenzothiazoleCatalystHCID 6880942,2'-Bipyridine-4,4'-dicarboxylic acidCatalystHCID 16211477Iridium trichloride hydrateCatalystHCID 679Dimethyl SulfoxideSolventHCID 6228DimethylformamideSolvent

Sources & evidence

ORD record
ord-46378b0b1db64378afa7310637adbc4a
Source dataset
Photodehalogenation_HTE_estimated_conv_at_5hr
Original link
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Linked notes

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