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1-(2-Bromo-4-fluorophenyl)ethan-1-one → 4'-Fluoroacetophenone

HRID 1704909
Notes
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Reaction equation

HRID 1704909 reaction equation
CC(=O)c1ccc(F)cc1Br.CCN(CC)c1ccc2oc(=O)c(-c3nc4ccccc4s3)cc2c1>CCN(C(C)C)C(C)C.CN(C)C=O.CS(C)=O.FC(F)(F)c1ccc(-c2nc3ccccc3s2)cc1.O.O=C(O)c1ccnc(-c2cc(C(=O)O)ccn2)c1.[Cl][Ir]([Cl])[Cl]>CC(=O)c1ccc(F)cc1.CCN(CC)c1ccc2oc(=O)c(-c3[nH+]c4ccccc4s3)cc2c1.[Br-]
ParticipantsSources & evidenceReaction notes

Participants

10

Reactant 2

HCID 27363041-(2-Bromo-4-fluorophenyl)ethan-1-oneHCID 206057453-(Benzo[d]thiazol-2-yl)-6-(diethylamino)-2H-chromen-2-one

Product 2

HCID 98284'-FluoroacetophenoneHCID 178463797HCID 178463797, compound

Reagents, catalysts & solvents 6

HCID 81531DiisopropylethylamineReagentHCID 6880942,2'-Bipyridine-4,4'-dicarboxylic acidCatalystHCID 148132702-[4-(Trifluoromethyl)phenyl]-1,3-benzothiazoleCatalystHCID 16211477Iridium trichloride hydrateCatalystHCID 679Dimethyl SulfoxideSolventHCID 6228DimethylformamideSolvent

Sources & evidence

ORD record
ord-f80b72cd85fd4756a185087dbd871783
Source dataset
Photodehalogenation_HTE_estimated_conv_at_5hr
DOI
10.1021/acscatal.0c02247
Original link
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Reaction notes

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