Acetate → 3-(3,5-Dichloro-phenyl)-acrylic acid tert butyl ester

HRID 185072

Reaction equation

HRID 185072 reaction equation
[C:10]([CH:11]=[CH2:12])(=[O:13])[O:14][C:15]([CH3:16])([CH3:17])[CH3:18].[CH2:26]([N+:27]([CH2:28][CH2:29][CH2:30][CH3:31])([CH2:32][CH2:33][CH2:34][CH3:35])[CH2:36][CH2:37][CH2:38][CH3:39])[CH2:40][CH2:41][CH3:42].[CH3:20][C:21](=[O:22])[O-:23].[Cl-:25].[Cl:1][c:2]1[cH:3][c:4]([I:9])[cH:5][c:6]([Cl:8])[cH:7]1.[K+:19].[O-:49][C:50]([CH3:51])=[O:52].[O-:53][C:54]([CH3:55])=[O:56].[O:43]=[CH:44][N:45]([CH3:46])[CH3:47].[OH2:24].[Pd+2:48]>>[Cl:1][c:2]1[cH:3][c:4]([CH:12]=[CH:11][C:10](=[O:13])[O:14][C:15]([CH3:16])([CH3:17])[CH3:18])[cH:5][c:6]([Cl:8])[cH:7]1

Participants

10

Reactant 9

HCID 175Acetate3×HCID 312ChlorideHCID 813Potassium CationHCID 962WaterHCID 6228DimethylformamideHCID 15458tert-Butyl acrylateHCID 16028TetrabutylammoniumHCID 764241,3-Dichloro-5-iodobenzeneHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)

Product 1

HCID 536582813-(3,5-Dichloro-phenyl)-acrylic acid tert butyl ester

Sources & evidence

ORD record
ord-0276941c34b94a5585590163aa0671cd
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (6/10)

Linked notes

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