4-Bromotoluene → [1,1'-Biphenyl]-2,5-dicarboxylic acid, 4'-methyl-, 2,5-dimethyl ester

HRID 197691

Reaction equation

HRID 197691 reaction equation
[Br:1][c:2]1[cH:3][cH:4][c:5]([CH3:8])[cH:6][cH:7]1.[C:9]([Li:10])([CH3:11])([CH3:12])[CH3:13].[CH3:14][O:15][C:16]([c:17]1[c:18]([Br:27])[cH:19][c:20]([C:21](=[O:22])[O:23][CH3:24])[cH:25][cH:26]1)=[O:28].[O:29]1[CH2:30][CH2:31][CH2:32][CH2:33]1>>[c:2]1(-[c:18]2[c:17]([C:16]([O:15][CH3:14])=[O:28])[cH:26][cH:25][c:20]([C:21](=[O:22])[O:23][CH3:24])[cH:19]2)[cH:3][cH:4][c:5]([CH3:8])[cH:6][cH:7]1

Participants

5

Reactant 4

HCID 78054-BromotolueneHCID 8028TetrahydrofuranHCID 87741Dimethyl 2-bromoterephthalateHCID 178418306HCID 178418306, compound

Product 1

HCID 105655[1,1'-Biphenyl]-2,5-dicarboxylic acid, 4'-methyl-, 2,5-dimethyl ester

Sources & evidence

ORD record
ord-f462f940027f4c4db189e9282929feaa
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (6/10)

Linked notes

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