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Chlorine Dioxide → Sodium sesquisulfate

HRID 1979887
Notes
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Reaction equation

HRID 1979887 reaction equation
Cl(=O)=O.[S:4](=[O:8])(=[O:7])([OH:6])[O-:5].[Na+:9]>O>[S:4]([OH:8])([OH:7])(=[O:6])=[O:5].[Na+:9].[S:4]([O-:8])([O-:7])(=[O:6])=[O:5].[S:4]([OH:8])([OH:7])(=[O:6])=[O:5].[Na+:9]
ParticipantsProcedureWorkupSources & evidenceReaction notes

Participants

4

Reactant 2

HCID 24870Chlorine DioxideHCID 516919Sodium Bisulfate

Product 1

HCID 19098072Sodium sesquisulfate

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

recycling the first stage acidic filtrate back to said chlorine dioxide generator and dissolving said first stage sodium bisulfate crystals in H2O to create a second stage solution for a second stage evaporator/crystallizer and heating said second stage solution to a prescribed temperature under a partial vacuum for a predetermined period of time to reduce the solution volume and then cooling said solution in the crystallizer to produce second stage sodium sesquisulfate crystals from which the second stage acidic filtrate is separated and recycled to said first stage evaporator/crystallizer, and

Workup

  1. dissolutiondissolving
  2. customfor a second stage evaporator/crystallizer
  3. temperatureheating
  4. temperaturecooling

Sources & evidence

ORD record
ord-96e5c7ebc94448ab9937f8d9498ad575
Source dataset
uspto-grants-1984_11
DOI
10.6084/m9.figshare.5104873.v1
Patent number
US04483740

Reaction notes

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On this pageParticipantsProcedureWorkupSources & evidenceReaction notes