Dimethyl Sulfoxide → Methyl 6-formylpyridine-3-carboxylate

HRID 2129750

Reaction equation

HRID 2129750 reaction equation
[CH3:1][O:2][C:3]([c:4]1[cH:5][n:6][c:7]([CH3:10])[cH:8][cH:9]1)=[O:11].[CH3:37][S:38]([CH3:39])=[O:40].[I:12].[I:13][C:14]([CH3:15])([CH3:16])[CH3:17].[Na+:25].[Na+:26].[Na+:36].[O-:27][S:28]([O-:29])(=[S:30])=[O:31].[O-:32][C:33]([OH:34])=[O:35].[OH:18][C:19]([C:20]([F:21])([F:22])[F:23])=[O:24]>>[CH3:1][O:2][C:3]([c:4]1[cH:5][n:6][c:7]([CH:10]=[O:18])[cH:8][cH:9]1)=[O:11]

Participants

9

Reactant 8

HCID 679Dimethyl SulfoxideHCID 769Bicarbonate IonHCID 923Sodium ion3×HCID 1084Thiosulfate ionHCID 6422Trifluoroacetic acidHCID 112062-Iodo-2-methylpropaneHCID 24841Hydrogen iodideHCID 231548Methyl 6-methylnicotinate

Product 1

HCID 586269Methyl 6-formylpyridine-3-carboxylate

Sources & evidence

ORD record
ord-f45207db51744b9c8b8e7bba95c553c8
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (4/10)

Linked notes

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