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Dioctylpyrocatechol → Catechol

HRID 256137
Notes
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Reaction equation

HRID 256137 reaction equation
[CH2:1]([C:9]1[C:10](CCCCCCCC)=[C:11]([OH:16])[C:12](=[CH:14][CH:15]=1)[OH:13])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7]C>CCCCC(COP(OCC(CCCC)CC)(O)=O)CC.[Cu]>[CH2:9]=[CH:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH3:7].[C:12]1([C:11](=[CH:10][CH:9]=[CH:15][CH:14]=1)[OH:16])[OH:13]
ParticipantsProcedureSources & evidenceReaction notes

Participants

5

Reactant 1

HCID 17969466Dioctylpyrocatechol

Product 2

HCID 289CatecholHCID 81251-Octene

Reagents, catalysts & solvents 2

HCID 23978CopperCatalystHCID 9275Bis(2-ethylhexyl) phosphateSolvent

Procedure

In the same way as the previous example, 100 ml of a copper solution was contacted with a 0.3M solution of dioctylpyrocatechol (100 ml) in ESCAID 100, obtained from the reaction of an excess of 1-octene with pyrocatechol.

Sources & evidence

ORD record
ord-159794877bcf4e21a4fa6aaa52787ce2
Source dataset
uspto-grants-1987_10
DOI
10.6084/m9.figshare.5104873.v1
Patent number
US04701311

Reaction notes

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On this pageParticipantsProcedureSources & evidenceReaction notes