Hydrazine hydrate (1:1) → Arabinosehydrazon

HRID 279931

Reaction equation

HRID 279931 reaction equation
[O:1]=[CH:2][C@H:3]([C@@H:5]([C@@H:7]([CH2:9]O)[OH:8])[OH:6])[OH:4].O.[NH2:12][NH2:13]>CO>[CH:9](=[N:12][NH2:13])[C@H:7]([C@@H:5]([C@@H:3]([CH2:2][OH:1])[OH:4])[OH:6])[OH:8]

Participants

4

Reactant 2

HCID 24654Hydrazine hydrate (1:1)HCID 66308D-Arabinose

Product 1

HCID 86740783Arabinosehydrazon

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

A solution of 4.0 g of D-arabinose in 10 ml of methanol and 10 ml of hydrazine hydrate was stirred overnight, then evaporated to dryness in vacuo. The residue was triturated with 25 ml of methanol and the solid was collected, giving 3.5 g of D-arabinose hydrazone.

Workup

  1. customevaporated to dryness in vacuo
  2. customThe residue was triturated with 25 ml of methanol
  3. customthe solid was collected

Sources & evidence

ORD record
ord-ebf88657c39e4ad8abc375b13788fe63
Source dataset
uspto-grants-1986_05
Patent number
US04587331

Linked notes

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