Azobisisobutyronitrile → Methacrylic Acid

HRID 346293

Reaction equation

HRID 346293 reaction equation
[C:1](OF)(=[O:4])[CH:2]=C.[C:7]([O-:12])(=[O:11])[C:8]([CH3:10])=[CH2:9].CC(N=NC(C#N)(C)C)(C#N)C>C1COCC1>[C:7]([OH:12])(=[O:11])[C:8]([CH3:10])=[CH2:9].[C:7]([O:12][CH2:2][CH2:1][OH:4])(=[O:11])[C:8]([CH3:10])=[CH2:9]

Participants

6

Reactant 3

HCID 6547AzobisisobutyronitrileHCID 87595MethacrylateHCID 21909953Fluoro acrylate

Product 2

HCID 4093Methacrylic AcidHCID 133602-Hydroxyethyl Methacrylate

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

This example illustrates conjoint use of the fluoro acrylate and methacrylate. 75.81 g (40.8 wt. %) of the perfluoroalkyl methacrylate (DuPont's Zonyl-TM), 72.3 g (38.9 wt. %) of the perfluoroalkyl acrylate (Hoechst-Celanese NUVA HF), 17.61 g (9.5 wt. %) of methacrylic acid, and 19.98 g (10.8 wt. %) of 2-hydroxyethyl methacrylate were polymerized in 300 ml THF, using 0.55 g AIBN as initiator, employing above-described procedure. Yield: 79.1%.

Sources & evidence

ORD record
ord-cd1e6f295915444e88010f80a06c0170
Source dataset
uspto-grants-1991_10
Patent number
US05061769

Linked notes

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