Sebacic Acid → Bis(tetrabutylammonium)sebacate

HRID 356567

Reaction equation

HRID 356567 reaction equation
[C:1]([OH:14])(=[O:13])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][C:10]([OH:12])=[O:11].[OH-].[CH2:16]([N+:20]([CH2:29][CH2:30][CH2:31][CH3:32])([CH2:25][CH2:26][CH2:27][CH3:28])[CH2:21][CH2:22][CH2:23][CH3:24])[CH2:17][CH2:18][CH3:19]>CO>[C:1]([O-:14])(=[O:13])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][C:10]([O-:12])=[O:11].[CH2:29]([N+:20]([CH2:16][CH2:17][CH2:18][CH3:19])([CH2:21][CH2:22][CH2:23][CH3:24])[CH2:25][CH2:26][CH2:27][CH3:28])[CH2:30][CH2:31][CH3:32].[CH2:29]([N+:20]([CH2:16][CH2:17][CH2:18][CH3:19])([CH2:21][CH2:22][CH2:23][CH3:24])[CH2:25][CH2:26][CH2:27][CH3:28])[CH2:30][CH2:31][CH3:32]

Participants

4

Reactant 2

HCID 5192Sebacic AcidHCID 2723671Tetrabutylammonium Hydroxide

Product 1

HCID 21903074Bis(tetrabutylammonium)sebacate

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

The procedure used was the same as described above by titration of sebacic acid (0.814 g, 4.02×10-3 mol) with 1M tetrabutylammonium hydroxide solution in methanol. After removal of solvent, a quantitative yield (2.75 g) of salt was obtained. FIG. 45 shows a 1H NMR spectrum and FIG. 46 shows a 13C NMR spectrum of the salt in CDCl3.

Workup

  1. customAfter removal of solvent

Sources & evidence

ORD record
ord-c329fd7522e44baeb9d30c19ddd27df0
Source dataset
uspto-grants-1998_11
Patent number
US05837381

Linked notes

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