Azobisisobutyronitrile → Allyl methacrylate
Reaction equation
C(N1CCCC1=O)=C.[C:9]([O:14][CH2:15][CH2:16][CH2:17]CCCCCCCCC)(=[O:13])[C:10]([CH3:12])=[CH2:11].N(C(C)(C)C#N)=NC(C)(C)C#N>O>[C:9]([O:14][CH2:15][CH:16]=[CH2:17])(=[O:13])[C:10]([CH3:12])=[CH2:11]Participants
6
Reactant 4
Product 1
Reagents, catalysts & solvents 1
Procedure
The dimer of allyl methacrylate, which was prepared according to Example 1, was added in the amount of 3 wt.-% (based on to the entire mixture) to the mixture containing 90 wt.-% N-vinylpyrrolidone and 10 wt.-% dodecyl methacrylate. The mixture was polymerized in a polypropylene mold at 60° C. for 16 h in the presence of 0.4 wt.-% azobisisobutyronitrile. The resulting gel contained, after swelling with water, 76 wt.-% water at G=0.048 MPa. The soluble extractable portion was 2%.
Workup
- additionwas added in the amount of 3 wt.-% (
Sources & evidence
- ORD record
- ord-0c898061a2e84a4b86bc75b954ef6864
- Source dataset
- uspto-grants-1986_08
- Patent number
- US04604440
Reaction notes
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