Azobisisobutyronitrile → Allyl methacrylate

HRID 364156

Reaction equation

HRID 364156 reaction equation
C(N1CCCC1=O)=C.[C:9]([O:14][CH2:15][CH2:16][CH2:17]CCCCCCCCC)(=[O:13])[C:10]([CH3:12])=[CH2:11].N(C(C)(C)C#N)=NC(C)(C)C#N>O>[C:9]([O:14][CH2:15][CH:16]=[CH2:17])(=[O:13])[C:10]([CH3:12])=[CH2:11]

Participants

6

Reactant 4

HCID 6547AzobisisobutyronitrileHCID 6917N-vinyl-2-pyrrolidoneHCID 8906Lauryl MethacrylateHCID 178435178HCID 178435178, compound

Product 1

HCID 7274Allyl methacrylate

Reagents, catalysts & solvents 1

HCID 962WaterSolvent2×

Procedure

The dimer of allyl methacrylate, which was prepared according to Example 1, was added in the amount of 3 wt.-% (based on to the entire mixture) to the mixture containing 90 wt.-% N-vinylpyrrolidone and 10 wt.-% dodecyl methacrylate. The mixture was polymerized in a polypropylene mold at 60° C. for 16 h in the presence of 0.4 wt.-% azobisisobutyronitrile. The resulting gel contained, after swelling with water, 76 wt.-% water at G=0.048 MPa. The soluble extractable portion was 2%.

Workup

  1. additionwas added in the amount of 3 wt.-% (

Sources & evidence

ORD record
ord-0c898061a2e84a4b86bc75b954ef6864
Source dataset
uspto-grants-1986_08
Patent number
US04604440

Linked notes

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