Azobisisobutyronitrile → Allyl methacrylate

HRID 364159

Reaction equation

HRID 364159 reaction equation
C(N1C[CH2:6][CH2:5][C:4]1=[O:8])=C.[C:9](OC(C)(C)C)(=[O:13])[C:10]([CH3:12])=[CH2:11].N(C(C)(C)C#N)=NC(C)(C)C#N>O>[C:9]([O:6][CH2:5][CH:4]=[CH2:8])(=[O:13])[C:10]([CH3:12])=[CH2:11]

Participants

6

Reactant 4

HCID 6547AzobisisobutyronitrileHCID 6917N-vinyl-2-pyrrolidoneHCID 11448tert-Butyl methacrylateHCID 178435178HCID 178435178, compound

Product 1

HCID 7274Allyl methacrylate

Reagents, catalysts & solvents 1

HCID 962WaterSolvent2×

Procedure

The dimer of allyl methacrylate, which was prepared according to Example 1, was added to the mixture containing 80 wt.-% N-vinylpyrrolidone and 20 wt.-% tert-butyl methacrylate in the amount of 1 wt.-% on the whole mixture. The mixture was polymerized in a polypropylene mold at 60° C. for 16 h in the presence of 0.4 wt.-% azobisisobutyronitrile. The resulting gel contained, after swelling with water, 67 wt.-% water at G=0.529 MPa.

Workup

  1. additionwas added to the mixture

Sources & evidence

ORD record
ord-315fd0e0fe13428fa1ac09c97485c2f1
Source dataset
uspto-grants-1986_08
Patent number
US04604440

Linked notes

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