Hydrochloric Acid → N-Methyl-N(4-t-Butylphenylthiosulfenyl) Carbamoyl Fluoride

Reaction equation

[C:1]([C:5]1[CH:10]=[CH:9][C:8]([SH:11])=[CH:7][CH:6]=1)([CH3:4])([CH3:3])[CH3:2].CN(Cl)C(F)=S.Cl.[CH3:19][N:20]([S:24]SC1C=CC(Cl)=CC=1)[C:21]([F:23])=[O:22]>CCCCC>[CH3:19][N:20]([S:24][S:11][C:8]1[CH:7]=[CH:6][C:5]([C:1]([CH3:4])([CH3:2])[CH3:3])=[CH:10][CH:9]=1)[C:21]([F:23])=[O:22]

Participants

Reactant 4

HCID 313Hydrochloric Acid

HCID 754544-Tert-Butylbenzenethiol

HCID 20327306N-methyl-N-chlorothiocarbamoyl fluoride

HCID 23333002N-methyl-N-(4-chlorophenylthiosulfenyl)carbamoyl fluoride

Product 1

HCID 23333006N-Methyl-N(4-t-Butylphenylthiosulfenyl) Carbamoyl Fluoride

Reagents, catalysts & solvents 1

Procedure

Prepared by reacting 0.5 g of 4-t-butylthiophenol in pentane with 0.44 g of N-methyl-N-chlorothiocarbamoyl fluoride. The reaction proceded with a vigorous exotherm and evolution of hydrochloric acid gas. The infrared and n.m.r. spectra of the product was identical to the material prepared by Method I.