Reaction equation
S(=O)(=O)(O)O.[OH:6][Si:7]([OH:9])=[O:8].[NH2:10][C:11]([NH2:13])=[O:12]>>[Si:7]([OH:12])([OH:9])([OH:6])[OH:8].[NH2:10][C:11]([NH2:13])=[O:12].[NH2:10][C:11]([NH2:13])=[O:12]Participants
Procedure
Clay is reacted with sulfuric acid, thereby producing metasilicic acid, which is recovered by filtration. About one mol of said metasilicic acid is mixed with 2 mols of urea, heated to 90° to 150° C. for 20 to 30 minutes, thereby producing white granules of diurea silicate. The said diurea silicate is added to an aqueous solution of hexamethylene tetramine in the ratio of 1:1.5 mols, heated to 70° to 110° C. for 20 to 90 minutes, thereby producing a clear thick solution of poly (formaldehyde diurea silicate) resin, and, upon further heating, a white resin is produced. The said white resin is soluble in acetic acid and produces a clear solution; the unreacted silicic acid is precipitated. The solution of poly (formaldehyde diurea silicate) resin forms a clear tough coating on wood.
Workup
- filtrationproducing metasilicic acid, which is recovered by filtration
- temperatureheated to 90° to 150° C. for 20 to 30 minutes
Sources & evidence
- ORD record
- ord-1764dfd111244b058eec066ec5b04c15
- Source dataset
- uspto-grants-1979_10
- Patent number
- US04169930
Linked notes
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