Triethylenetetramine → HCID 20327359, compound

HRID 462325

Reaction equation

[ClH:1].Cl.Cl.[CH:4]12[CH2:10][CH:7]([CH2:8][CH2:9]1)[CH2:6][CH:5]2[CH2:11]C(NCCCNCCCN)CC1CC2CC1CC2.C12CC(CC1)C[CH:31]2[CH2:37][C:38](=O)[CH2:39][CH:40]1[CH2:45][CH:44]2[CH2:46][CH:41]1[CH2:42][CH2:43]2.[CH2:48]([CH2:51][NH:52][CH2:53][CH2:54][CH2:55][NH2:56])[CH2:49][NH2:50].Cl.Cl.Cl.Cl.C12CC(CC1)CC2CC(NCCNCCNCCN)CC1CC2CC1CC2.NCCNCCNCCN.Cl.Cl.Cl.C12CC(CC1)CC2CCCC(NCCCNCCCN)CCCC1CC2CC1CC2.C12CC(CC1)CC2CCCC(=O)CCCC1CC2CC1CC2.Cl.Cl.Cl.C12CC(CC1)CC2C(CC(NCCCNCCCN)CC(C1CC2CC1CC2)C)C.C12CC(CC1)CC2C(CC(=O)CC(C1CC2CC1CC2)C)C>>[ClH:1].[ClH:1].[ClH:1].[CH:41]12[CH2:46][CH:44]([CH2:43][CH2:42]1)[CH2:45][CH:40]2[CH2:39][CH2:38][CH:37]([NH:50][CH2:49][CH2:48][CH2:51][NH:52][CH2:53][CH2:54][CH2:55][NH2:56])[CH2:31][CH2:11][CH:5]1[CH2:6][CH:7]2[CH2:10][CH:4]1[CH2:9][CH2:8]2

Participants

Reactant 9

HCID 5565Triethylenetetramine

HCID 5942Bis(3-aminopropyl)amine3×

HCID 19850365HCID 19850365, compound2×

HCID 20327329HCID 20327329, compound

HCID 20327336HCID 20327336, compound

HCID 203273501-[1,7-Di-(2-norbornyl)-4-heptyl]-1,5,9-triazanonane trihydrochloride

HCID 20327367HCID 20327367, compound

HCID 20327369HCID 20327369, compound

HCID 21390616HCID 21390616, compound

Product 1

HCID 20327359HCID 20327359, compound

Procedure

Also prepared by this method in an analogous manner regarding molar quantities and reaction conditions are 1-[1,3-di-(2-norbornyl)-2-propyl]-1,5,9-triazanonane trihydrochloride from 1,3-di-(2-norbornyl)-2-propanone and 3,3'-iminobispropylamine; 1-[1,3-di-2-norbornyl-2-propyl]-1,4,7,10-tetraazadecane tetrahydrochloride from 1,3-di-(2-norbornyl)-2-propanone and triethylenetetramine; 1-[1,7-di-(2-norbornyl)-4-heptyl]-1,5,9-triazanonane trihydrochloride from 1,7-di-(2-norbornyl)-4-heptanone and 3,3'-iminobispropylamine and 1-[2,6-di-(2-norbornyl)-4-heptyl]-1,5,9-triazanonane trihydrochloride from 2,6-di-(2-norbornyl)-4-heptanone and 3,3'-iminobispropylamine.

Workup

customAlso prepared by this method in an analogous manner
customquantities and reaction conditions

Sources & evidence

ORD record: ord-4c582c66c1bb447399a117c4566a4faf
Source dataset: uspto-grants-1977_12
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04065497

Linked notes

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