1-Octene → Gamma-Decalactone

HRID 46746

Reaction equation

HRID 46746 reaction equation
[CH3:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH:7]=[CH2:8].[C:9]([O-:12])(=[O:11])[CH3:10].[K+]>C(O)(=O)C>[CH2:6]([CH:7]1[O:12][C:9](=[O:11])[CH2:10][CH2:8]1)[CH2:5][CH2:4][CH2:3][CH2:2][CH3:1]

Participants

4

Reactant 2

HCID 81251-OcteneHCID 517044Potassium Acetate

Product 1

HCID 12813Gamma-DecalactoneYield 48%

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

Octene-1 in an amount of 2.2 g. and 23.6 g. of ceric ammonium nitrate, Ce(NH4)2 (NO3)6, were refluxed under nitrogen in 200 ml. glacial acetic acid containing 60 g. potassium acetate for less than 0.5 hour, there being obtained a 48% yield of gamma-n-hexyl-butyrolactone.

Sources & evidence

ORD record
ord-2c03d4a37bfe48c9975a949c07039ab8
Source dataset
uspto-grants-1979_11
Patent number
US04175089

Linked notes

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