Isopropanol → Sodium dipentyldithiocarbamate

HRID 481282

Reaction equation

HRID 481282 reaction equation
[CH2:1]([NH:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[CH2:2][CH2:3][CH2:4][CH3:5].[OH-].[Na+:13].CC(O)C.[C:18](=[S:20])=[S:19]>>[CH2:7]([N:6]([CH2:1][CH2:2][CH2:3][CH2:4][CH3:5])[C:18](=[S:19])[S-:20])[CH2:8][CH2:9][CH2:10][CH3:11].[Na+:13]

Participants

5

Reactant 4

HCID 3776IsopropanolHCID 6348Carbon Disulfide2×HCID 14798Sodium HydroxideHCID 16316Dipentylamine

Product 1

HCID 23680238Sodium dipentyldithiocarbamate

Procedure

To a 250 mL 3-neck round bottom reaction flask equipped with an overhead stirrer, a thermocouple probe, a reflux condenser, a Claisen adapter, and a 25 mL addition funnel, 30.0 g (0.19 mol) of diamyl amine, 15.3 g of a 50 weight percent NaOH solution (0.19 mol NaOH) and 100 mL reagent 2-propanol was added. 12.5 mL (0.21 mol) carbon disulfide was charged to the addition funnel. Carbon disulfide was added over a half-hour period. The reaction temperature was maintained at 25°-30° C. The product was post-reacted at 25° C. for 1 hour.

Workup

  1. customTo a 250 mL 3-neck round bottom reaction flask equipped with an overhead stirrer
  2. additionwas added
  3. temperatureThe reaction temperature was maintained at 25°-30° C
  4. customThe product was post-reacted at 25° C. for 1 hour

Sources & evidence

ORD record
ord-ba059865d1854ecd80b1f38fe654ffd4
Source dataset
uspto-grants-1998_08
Patent number
US05789357

Linked notes

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