Acetonitrile → HCID 11123531, compound

HRID 581185

Reaction equation

HRID 581185 reaction equation
[NH2:1][C:2]1[C:15]2[C:14](=[O:16])[C:13]3[C:8](=[CH:9][CH:10]=[CH:11][CH:12]=3)[C:7](=[O:17])[C:6]=2[C:5]([NH:18]C2C=CC=CC=2)=[CH:4][CH:3]=1.[CH:25]([C:27]1[CH:34]=[CH:33][C:30]([CH2:31]Cl)=[CH:29][CH:28]=1)=[CH2:26].N1[C:40]([CH3:41])=[CH:39][CH:38]=[CH:37][C:36]=1[CH3:42].[C:43](#N)[CH3:44]>>[CH:25]([C:27]1[CH:34]=[CH:33][C:30]([CH2:31][NH:18][C:5]2[C:6]3[C:7](=[O:17])[C:8]4[C:13](=[CH:12][CH:11]=[CH:10][CH:9]=4)[C:14](=[O:16])[C:15]=3[C:2]([NH:1][CH2:42][C:36]3[CH:41]=[CH:40][C:39]([CH:43]=[CH2:44])=[CH:38][CH:37]=3)=[CH:3][CH:4]=2)=[CH:29][CH:28]=1)=[CH2:26]

Participants

5

Reactant 4

HCID 6342AcetonitrileHCID 79372,6-LutidineHCID 20419Solvent Blue 68HCID 74126p-Vinylbenzyl chloride

Product 1

HCID 11123531HCID 11123531, compound

Procedure

Reaction was performed by using the following reactants, catalyst and solvent: 1-amino-4-anilinoanthraquinone (precursor, 2.5 g, 7.96 mmol), 4-vinylbenzyl chloride (1.25 g, 8.22 mmol), 2,6-lutidine (a catalyst, 0.88 g, 8.22 mmol) and acetonitrile (solvent, 25 ml) in a reaction apparatus similar to that of Example 1. After completion of the reaction, the product was purified in the same manner as in Example 1 to afford the desired reactive dye, BD-4 (Yield: 67%). ##STR9##

Workup

  1. customReaction
  2. customAfter completion of the reaction
  3. customthe product was purified in the same manner as in Example 1
  4. customto afford the desired reactive dye, BD-4 (Yield: 67%)

Sources & evidence

ORD record
ord-c489318c97f3481899e8a8ad54ac2ea8
Source dataset
uspto-grants-1999_07
Patent number
US05919880

Linked notes

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