Chloride → N,N-Dimethyl-N-(prop-2-en-1-yl)hexadecan-1-aminium chloride

HRID 596540

Reaction equation

[CH2:1]([Cl:4])[CH:2]=[CH2:3].[CH3:5][N:6]([CH3:23])[CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22].[Cl-]>>[Cl-:4].[CH2:1]([N+:6]([CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22])([CH3:5])[CH3:23])[CH:2]=[CH2:3]

Participants

Reactant 3

HCID 312Chloride

HCID 7850Allyl chloride

HCID 16221Dimethylhexadecylamine

Product 1

HCID 20503036N,N-Dimethyl-N-(prop-2-en-1-yl)hexadecan-1-aminium chloride

Procedure

Allyl hexadecyl dimethyl ammonium chloride was prepared by reacting allyl chloride and dimethyl hexadecyl amine as set forth in Example 1. 17.8 grams of the chloride in 23.5% aqueous solution were treated with a stoichiometric excess of AgF in aqueous solution until analysis of the filtrate showed only a trace of chloride ion present. Excess silver ion was removed by the careful addition of NaCl, AgCl being removed by filtration.

Workup

customExcess silver ion was removed by the careful addition of NaCl, AgCl being
customremoved by filtration

Sources & evidence

ORD record: ord-a17a8510cadc46f49c66ddc06659ad6c
Source dataset: uspto-grants-1977_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04011259

Linked notes

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