cis,cis-1,5-Cyclooctadiene → Tetradeca-1,5,9-triene

Reaction equation

[CH:1]1[CH2:8][CH2:7][CH:6]=[CH:5][CH2:4][CH2:3][CH:2]=1.[CH2:9]=[CH:10][CH2:11][CH2:12][CH2:13][CH3:14]>>[CH2:9]=[CH:10][CH2:11][CH2:12][CH:13]=[CH:14][CH2:1][CH2:8][CH:7]=[CH:6][CH2:5][CH2:4][CH2:3][CH3:2]

Participants

Reactant 2

HCID 8135cis,cis-1,5-Cyclooctadiene

HCID 115971-Hexene

Product 1

HCID 54124585Tetradeca-1,5,9-triene

Procedure

disproportionating 1,5-cyclooctadiene and 1-hexene in the presence of a disproportionation catalyst under disproportionation conditions suitable to give 1,5,9-tetradecatriene,

Sources & evidence

ORD record: ord-69ea37ec331249f3a554f60dafe65239
Source dataset: uspto-grants-1986_09
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04609498

Reaction notes

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