tert-Butyl hydroperoxide → 1-[2-(1,1-Dimethylpropyl)diazenyl]cyclohexanecarbonitrile

HRID 649250

Reaction equation

HRID 649250 reaction equation
N(C(C)(C)C#N)=N[C:3](C)(C)C#N.[N:13]([C:24]([C:31]#N)([CH3:30])[CH2:25][CH2:26]C(O)=O)=[N:14][C:15]([C:22]#[N:23])([CH3:21])[CH2:16][CH2:17][C:18](O)=O.N(C(C)(CC(C)C)C#N)=NC(C)(CC(C)C)C#N.C(OO)(C)(C)C.[O-]O.C1(C(C)C)C=CC=CC=1>>[C:24]([N:13]=[N:14][C:15]1([C:22]#[N:23])[CH2:16][CH2:17][CH2:18][CH2:3][CH2:21]1)([CH2:25][CH3:26])([CH3:30])[CH3:31]

Participants

6

Reactant 5

HCID 6410tert-Butyl hydroperoxideHCID 6547AzobisisobutyronitrileHCID 915372,2'-Azobis(2,4-dimethylvaleronitrile)HCID 929384,4-Azobis(4-cyanovaleric acid)HCID 53627471Cumen hydroperoxide

Product 1

HCID 919321-[2-(1,1-Dimethylpropyl)diazenyl]cyclohexanecarbonitrile

Procedure

Of these oil-soluble initiators, the most preferable due to commercial availability are 2,2'-azobis(isobutyronitrile), 4,4'-azobis(4-cyanopentanoic acid), 2,2'-azobis-(2,4-dimethylvaleronitrile), t-butyl hydroperoxide, cumene hydroperoxide, benzoyl peroxide amnd lauroyl peroxide.

Sources & evidence

ORD record
ord-6bf7dd0b82dd4659a6b73634ff077e0f
Source dataset
uspto-grants-1988_04
Patent number
US04739008

Linked notes

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