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Dimethyl Sulfoxide → 3-[[(1,1-Dimethylethyl)dimethylsilyl]oxy]tetrahydro-4-methoxy-5-methyl-2H-pyran-2-carboxaldehyde

HRID 664858
Notes
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Reaction equation

HRID 664858 reaction equation
[C:11]([CH3:12])([CH3:13])([CH3:14])[Si:15]([O:16][CH:17]1[CH:18]([CH2:26][OH:27])[O:19][CH2:20][CH:21]([CH3:25])[CH:22]1[O:23][CH3:24])([CH3:28])[CH3:29].[CH3:30][CH2:31][N:32]([CH2:33][CH3:34])[CH2:35][CH3:36].[CH3:7][S:8]([CH3:9])=[O:10].[Cl:1][C:2]([C:3]([Cl:4])=[O:5])=[O:6].[Cl:37][CH2:38][Cl:39]>>[C:11]([CH3:12])([CH3:13])([CH3:14])[Si:15]([O:16][CH:17]1[CH:18]([CH:26]=[O:27])[O:19][CH2:20][CH:21]([CH3:25])[CH:22]1[O:23][CH3:24])([CH3:28])[CH3:29]
ParticipantsSources & evidenceReaction notes

Participants

6

Reactant 5

HCID 679Dimethyl SulfoxideHCID 6344DichloromethaneHCID 8471TriethylamineHCID 65578Oxalyl chlorideHCID 196996953-[[(1,1-Dimethylethyl)dimethylsilyl]oxy]tetrahydro-4-methoxy-5-methyl-2H-pyran-2-methanol

Product 1

HCID 19699692
On this pageParticipantsSources & evidenceReaction notes
3-[[(1,1-Dimethylethyl)dimethylsilyl]oxy]tetrahydro-4-methoxy-5-methyl-2H-pyran-2-carboxaldehyde

Sources & evidence

ORD record
ord-d999b8b4046b4c018f6055e63e43c440
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (3/10)
DOI
10.1039/C8SC04228D

Reaction notes

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