2-Nitropropane → HCID 178430959, compound
Reaction equation
[N+:1]([CH:4]([CH3:6])[CH3:5])([O-:3])=O.[CH:7]1[CH:15]=[CH:14][C:13]2[C:9](=[N:10][O:11][N+]=2[O-])[CH:8]=1.C(NCC)C>O1CCCC1>[CH3:5][C:4]1([CH3:6])[N+:1]([O-:3])=[C:13]2[CH:14]=[CH:15][CH:7]=[CH:8][C:9]2=[N+:10]1[O-:11]Participants
5
Reactant 3
Product 1
Reagents, catalysts & solvents 1
Procedure
To a mixture containing 2-nitropropane (10.7 g., 0.12 moles), benzofuroxan (13.6 g., 0.10 moles) and tetrahydrofuran (50 ml.) is added dropwise diethylamine (8.7 g., 0.12 mole). The reaction temperature rises during addition. Upon completion of addition, the reaction mixture is allowed to sit overnight at room temperature.
Workup
- additionThe reaction temperature rises during addition
- additionUpon completion of addition
Sources & evidence
- ORD record
- ord-1c8ab1a20a294172a812417cba9eb226
- Source dataset
- uspto-grants-1982_08
- Patent number
- US04343942
Reaction notes
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