2-Nitropropane → HCID 178430959, compound

HRID 66957

Reaction equation

HRID 66957 reaction equation
[N+:1]([CH:4]([CH3:6])[CH3:5])([O-:3])=O.[CH:7]1[CH:15]=[CH:14][C:13]2[C:9](=[N:10][O:11][N+]=2[O-])[CH:8]=1.C(NCC)C>O1CCCC1>[CH3:5][C:4]1([CH3:6])[N+:1]([O-:3])=[C:13]2[CH:14]=[CH:15][CH:7]=[CH:8][C:9]2=[N+:10]1[O-:11]

Participants

5

Reactant 3

HCID 3982-NitropropaneHCID 8021DiethylamineHCID 68075Benzofuroxan

Product 1

HCID 178430959HCID 178430959, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

To a mixture containing 2-nitropropane (10.7 g., 0.12 moles), benzofuroxan (13.6 g., 0.10 moles) and tetrahydrofuran (50 ml.) is added dropwise diethylamine (8.7 g., 0.12 mole). The reaction temperature rises during addition. Upon completion of addition, the reaction mixture is allowed to sit overnight at room temperature.

Workup

  1. additionThe reaction temperature rises during addition
  2. additionUpon completion of addition

Sources & evidence

ORD record
ord-1c8ab1a20a294172a812417cba9eb226
Source dataset
uspto-grants-1982_08
Patent number
US04343942

Linked notes

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