Ammonia → HCID 178474349, compound

HRID 729191

Reaction equation

HRID 729191 reaction equation
[NH2:1][C:2]1[C:3](=[O:15])[N:4]([C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)[N:5]([CH3:8])[C:6]=1[CH3:7].[OH:16][C:17]1[CH:18]=[C:19]([NH:23][C:24](=[O:26])[CH3:25])[CH:20]=[CH:21][CH:22]=1.N>O.CC(O)C.[Fe-3](C#N)(C#N)(C#N)(C#N)(C#N)C#N.[K+].[K+].[K+]>[CH3:8][N:5]1[C:6]([CH3:7])=[C:2](/[N:1]=[C:20]2\[CH:21]=[CH:22][C:17](=[O:16])[CH:18]=[C:19]\2[NH:23][C:24](=[O:26])[CH3:25])[C:3](=[O:15])[N:4]1[C:9]1[CH:10]=[CH:11][CH:12]=[CH:13][CH:14]=1

Participants

7

Reactant 3

HCID 222AmmoniaHCID 21514-AminoantipyrineHCID 121243-Hydroxyacetanilide

Product 1

HCID 178474349HCID 178474349, compound

Reagents, catalysts & solvents 3

HCID 178511488HCID 178511488, compoundCatalystHCID 962WaterSolventHCID 3776IsopropanolSolvent

Procedure

10 mmol of 4-amino-1,5-dimethyl-2-phenyl-1,2-dihydro-3H-pyrazol-3-one was dissolved in 30 ml of water. This solution was admixed with 10 mmol of N-(3-hydroxyphenyl)acetamide in solution in 30 ml of 2-propanol, 3 ml of 20% aqueous ammonia and 22 mmol of potassium ferricyanide at a temperature ranging from 5 to 10° C.

Workup

  1. customranging from 5 to 10° C.

Sources & evidence

ORD record
ord-5b8e72a69e2f47ab8ec4826f10a43cbf
Source dataset
uspto-grants-2009_09
Patent number
US07582123B2

Linked notes

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