Hydrochloric Acid → Dimethyl 3-thienylmalonate

HRID 810107

Reaction equation

HRID 810107 reaction equation
[C:1]([CH2:2][C:3](=[O:4])[O:5][CH3:6])(=[O:7])[O:8][CH3:9].[ClH:18].[Cu:29][Br:30].[H-:11].[I:12][c:13]1[cH:14][s:15][cH:16][cH:17]1.[Na+:10].[OH2:31].[cH:19]1[cH:20][c:21]2[c:22]([n:23][cH:24][cH:25][cH:26]2)[cH:27][cH:28]1>>[C:1]([CH:2]([C:3](=[O:4])[O:5][CH3:6])[c:13]1[cH:14][s:15][cH:16][cH:17]1)(=[O:7])[O:8][CH3:9]

Participants

9

Reactant 8

HCID 313Hydrochloric AcidHCID 923Sodium ionHCID 962WaterHCID 7047QuinolineHCID 7943Dimethyl malonateHCID 24593copper(I) bromideHCID 663323-IodothiopheneHCID 166653Hydride

Product 1

HCID 12509453Dimethyl 3-thienylmalonate

Sources & evidence

ORD record
ord-db405d295d024b159d40b90f705caae6
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Linked notes

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