Bicarbonate Ion → 5-methyl-6,7-dihydro-1-benzothiophen-4(5H)-one

HRID 821565

Reaction equation

HRID 821565 reaction equation
[C:21](=[O:22])([OH:23])[O-:24].[CH:11]([N-:12][CH:13]([CH3:14])[CH3:15])([CH3:16])[CH3:17].[I:19][CH3:20].[Li+:18].[Na+:25].[O:26]1[CH2:27][CH2:28][CH2:29][CH2:30]1.[s:1]1[cH:2][cH:3][c:4]2[c:5]1[CH2:6][CH2:7][CH2:8][C:9]2=[O:10]>>[s:1]1[cH:2][cH:3][c:4]2[c:5]1[CH2:6][CH2:7][CH:8]([CH3:11])[C:9]2=[O:10]

Participants

8

Reactant 7

HCID 769Bicarbonate IonHCID 923Sodium ionHCID 6328Methyl iodideHCID 8028TetrahydrofuranHCID 28486Lithium ionHCID 834184,5,6,7-Tetrahydro-4-oxothionaphtheneHCID 5062348Diisopropylamide

Product 1

HCID 154115085-methyl-6,7-dihydro-1-benzothiophen-4(5H)-one

Sources & evidence

ORD record
ord-aa8d9a3d447f4568a0fc23d6fdb6fc9e
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Linked notes

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