Ethylene Oxide → Bisphenol A diglycidyl ether

HRID 885607

Reaction equation

[C:1]([O:5][CH2:6][CH2:7][CH2:8]CO)(=O)[CH:2]=C.[CH2:11]1[O:13][CH2:12]1.[CH2:14]1[O:17][CH:15]1[CH3:16].[OH:18][C:19]1[CH:24]=[CH:23][C:22]([C:25]([C:28]2[CH:33]=[CH:32][C:31]([OH:34])=[CH:30][CH:29]=2)([CH3:27])[CH3:26])=[CH:21][CH:20]=1>>[CH3:26][C:25]([C:28]1[CH:29]=[CH:30][C:31]([O:34][CH2:8][CH:7]2[O:5][CH2:6]2)=[CH:32][CH:33]=1)([C:22]1[CH:21]=[CH:20][C:19]([O:18][CH2:16][CH:15]2[O:17][CH2:14]2)=[CH:24][CH:23]=1)[CH3:27].[CH:15]([O:17][CH2:14][CH2:11][O:13][CH2:12][CH2:19][O:18][CH2:7][CH2:6][O:5][CH:1]=[CH2:2])=[CH2:16]

Participants

Reactant 4

HCID 6354Ethylene Oxide2×

HCID 6378Propylene Oxide2×

HCID 6623Bisphenol A

HCID 755884-Hydroxybutyl acrylate

Product 2

HCID 2286Bisphenol A diglycidyl ether

HCID 3033992Triethylene glycol divinyl ether

Procedure

Specific examples of the component (B) include: (meth)acrylates having an alkyl group such as butyl (meth)acrylate, isobutyl (meth)acrylate, t-butyl (meth)acrylate, pentyl (meth)acrylate, amyl (meth)acrylate, isoamyl (meth)acrylate, hexyl (meth)acrylate, heptyl (meth)acrylate, octyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, iso-octyl (meth)acrylate, nonyl (meth)acrylate, iso-nonyl (meth)acrylate, decyl (meth)acrylate, iso-decyl (meth)acrylate, undecyl (meth)acrylate, dodecyl (meth)acrylate, and lauryl (meth)acrylate; alicyclic structure-containing (meth)acrylates such as isobornyl (meth)acrylate, bornyl (meth)acrylate, tricyclodecanyl (meth)acrylate, dicyclopentanyl (meth)acrylate, dicyclopentenyl (meth)acrylate, 4-butylcyclohexyl (meth)acrylate, and cyclohexyl (meth)acrylate; (meth)acrylate having an aromatic ring such as benzyl (meth)acrylate; other monofunctional (meth)acrylates such as 2-hydroxyethyl (meth)acrylate, 2-hydroxypropyl (meth)acrylate, 4-hydroxybutyl acrylate, stearyl (meth)acrylate, iso-stearyl (meth)acrylate, tetrahydrofurfuryl (meth)acrylate, polyethylene glycol mono(meth)acrylate, polypropylene glycol mono(meth)acrylate, methoxyethylene glycol (meth)acrylate, ethoxyethyl (meth)acrylate, methoxypolyethylene glycol (meth)acrylate, methoxy polypropylene glycol (meth)acrylate, dimethylaminoethyl (meth)acrylate, diethylaminoethyl (meth)acrylate, and 7-amino-3,7-dimethyloctyl (meth)acrylate; polyfunctional (meth)acrylates such as trimethylolpropane tri(meth)acrylate, pentaerythritol tri(meth)acrylate, ethylene glycol di(meth)acrylate, tetraethylene glycol di(meth)acrylate, polyethylene glycol di(meth)acrylate, 1,4-butanediol di(meth)acrylate, 1,6-hexanediol di(meth)acrylate, neopentyl glycol di(meth)acrylate, trimethylolpropanetrioxyethyl (meth)acrylate, tris(2-hydroxyethyl)isocyanurate tri(meth)acrylate, tris(2-hydroxyethyl)isocyanurate di(meth)acrylate, tricyclodecanedimethanol di(meth)acrylate, di(meth)acrylate of ethylene oxide or propylene oxide addition diol of bisphenol A, di(meth)acrylate of ethylene oxide or propylene oxide addition diol of hydrogenated bisphenol A, epoxy (meth)acrylate obtained by the addition of (meth)acrylate to diglycidyl ether of bisphenol A, triethylene glycol divinyl ether, and the like.

Sources & evidence

ORD record: ord-de45b188d4084a4fab4ff68ab750bd85
Source dataset: uspto-grants-2012_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08242202B2

Linked notes

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