Acetone → 3-bromo-6-iodo-4H-thieno[3,2-b]pyrrole-5-carboxylic acid methyl ester

HRID 88562

Reaction equation

HRID 88562 reaction equation
[CH3:11][O:12][C:13](=[O:14])[c:15]1[cH:16][c:17]2[c:18]([nH:19]1)[c:20]([Br:23])[cH:21][s:22]2.[CH3:30][C:31](=[O:32])[CH3:33].[Cl:1][N:2]1[C:3](=[O:4])[CH2:5][CH2:6][C:7]1=[O:8].[I-:10].[Na+:28].[Na+:29].[Na+:9].[S:24]([O-:25])([O-:26])=[O:27]>>[I:10][c:16]1[c:15]([C:13]([O:12][CH3:11])=[O:14])[nH:19][c:18]2[c:17]1[s:22][cH:21][c:20]2[Br:23]

Participants

7

Reactant 6

HCID 180AcetoneHCID 923Sodium ion3×HCID 1099SulfiteHCID 30165Iodide IonHCID 31398ChlorosuccinimideHCID 44118324Methyl 3-bromo-4H-thieno[3,2-b]pyrrole-5-carboxylate

Product 1

HCID 583104013-bromo-6-iodo-4H-thieno[3,2-b]pyrrole-5-carboxylic acid methyl ester

Sources & evidence

ORD record
ord-4b8f737afa854b04bb096058ab6d5783
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (2/10)

Linked notes

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